NCERT MOST IMPORTANT QUESTIONS CLASS – 1 | CHEMISTRY IMPORTANT QUESTIONS | CHAPTER – 13 | THE SOLID STATE | EDUGROWN |

In This Post we are  providing Chapter- 1 THE SOLID STATE NCERT MOST IMPORTANT QUESTIONS for Class 12 CHEMISTRY which will be beneficial for students. These solutions are updated according to 2021-22 syllabus. These MCQS  can be really helpful in the preparation of Board exams and will provide you with a brief knowledge of the chapter

NCERT MOST IMPORTANT QUESTIONS ON THE SOLID STATE

Question 1.
Give reason:
(a) Why is Frenkel defect found in AgCI?
(b) What is the difference between phosphorus doped and gallium doped silicon semiconductors? (CBSE Sample Paper 2011)
Answer:
(a) Due to small size of Ag⁺ ion, it can fit into interstitial sites.
(b) Phosphorus doped silicon is n-type semiconductor while gallium doped silicon is p-type semiconductor.

Question 2.
Why does LiCl acquire pink colour when heated in Li vapours? (CBSE Sample Paper 2011)
Answer:
On heating LiCl in Li vapours, the excess of Li atoms deposit on the surface of the crystal. The CT ions diffuse to the surface of the crystal and combine with Li atoms to form LiCl. The electrons produced by ionisation of Li atoms diffuse into the crystal and get trapped at anion vacancies called F-centres. These absorb energy from visible light and radiate pink colour.

Question 3.
Account for the following:
(i) Schottky defects lower the density of related solids.
(ii) Conductivity of silicon increases on doping it with phosphorus. (C.B.S.E. 2013)
Answer:
(i) In Schottky defect, there are holes due to missing cations and anions. Due to the presence of holes in solid, the density decreases.

(ii) Pure silicon has a network lattice in which all the four valence electrons are bonded to four other atoms. Therefore, it is an insulator. However, when silicon is doped with phosphorus having five valence electrons, the impurity leads to excess of electrons after forming four covalent bonds like silicon. The extra electrons serve to conductivity and therefore, the conductivity of silicon doped with phosphorus increases.

Question 4.
(i) What type of non-stoichiometric point defect is responsible for the pink colour of LiCl?
Answer:
Metal excess defect due to anion vacancies filled by free electrons i.e. F-centres.

(ii) What type of stoichiometric defect is shown by NaCI?
Answer:
Schottky defect.

OR

How will you distinguish between the following pairs of terms:
(i) Tetrahedral and octahedral voids
Answer:
Tetrahedral void is surrounded by 4 constituent particles (atoms, molecules or ions). Octahedral void is surrounded by 6 constituent particles (atoms, molecules or ions).

(ii) Crystal lattice and unit cell? (C.B.S.E. 2014)
Answer:
A regular three dimensional arrangement of points in space is called crystal lattice.
The smallest repeating pattern in crystal lattice which when repeated in three dimensional space gives the entire lattice is called the unit cell.

Question 5.
An element crystallises in a fcc lattice with cell edge of 250 pm. Calculate its density if 300 g of this element contain 2 × 10²⁴ atoms.
Answer:
Length of edge, a = 250 pm = 250 × 10^-12 m
= 250 × 10^-10 cm
Volume of unit cell = (250 × 10^-10 cm)³
= 15.625 × 10^-24 cm³
Mass of unit cell = No. of atoms in unit cell × Mass of each atom
Since the element has fcc arrangement, the number of atoms per unit cell, Z = 4
Mass of an atom = \(\frac{300}{2 \times 10^{24}}\) g
∴ Mass of unit cell = \(\frac{300}{2 \times 10^{24}}\) x 4
= 6.0 × 10^-22 g

Question 6.
How can you determine the atomic mass of an unknown metal if you know its density and the dimension of its unit cell? Explain.
Answer:
Consider a unit cell of edge a cm
Volume of unit cell = a³ cm³

Mass of unit cell = No. of atoms in a unit cell × Mass of each atom = Z × m …… (ii)
Mass of an atom present in a unit cell

Knowing density (d), edge length (a), number of atoms per unit cell (Z) and Avogadro’s number (6.02 × 10²³), atomic mass can be calculated.

Question 7.
ZnO turns yellow on heating. Why?
Answer:
When ZnO is heated, it loses oxygen as:

The Zn²⁺ ions are entrapped in the interstitial sites and electrons are entrapped in the neighbouring interstitial sites to maintain electrical neutrality. This results in metal excess defect. Due to the presence of free electrons in the interstitial sites the colour is yellow.

Question 8.
(a) What type of semiconductor is obtained when silicon is doped with boron?
Answer:
(a) When silicon is doped with boron having three valence electrons, the bonds formed create electron deficient sites called holes. Under the influence of applied electric field, one electron from neighbouring atom moves to fill the hole but creates another hole at its own place. Therefore, the electrical conductance is due to movement of positive holes. Therefore, this type of semi-conductor is called p-type semi-conductor.

(b) What type of magnetism is shown in the following alignment of magnetic moments?
↑    ↑    ↑    ↑   ↑   ↑    ↑
Answer:
Ferromagnetic.

(c) What type of point defect is produced when AgCI is doped with CdCl₂?
Answer:
CdCl₂ on adding to AgCl introduces impurity defect. The addition of one Cd²⁺ ion will replace two Ag⁺ ions to maintain electrical neutrality. One of the positions of Ag⁺ will be occupied by Cd²⁺ ion and the other will be left as a hole. Thus, a hole is created similar to Schottky defect.

Question 9.
Account for the following:
(i) Schottky defects lower the density of related solids.
Answer:
In Schottky defect, there are holes due to missing cations and anions. Due to the presence of holes in solid, the density decreases.

(ii) Conductivity of silicon increases on doping it with phosphorus.
Answer:
Pure silicon has a network lattice in which all the four valence electrons are bonded to four other atoms. Therefore, it is an insulator. However, when silicon is doped with phosphorus (s²p³) having five valence electrons, the impurity leads to excess of electrons after forming four covalent bonds like silicon. The extra electrons serve to conductivity and therefore, the conductivity of silicon doped with phosphorus increases.

Question 10.
Examine the given defective crystal

Answer the following questions:
(i) What type of stoichiometric defect is shown by the crystal?
Answer:
Schottky defect

(ii) How is the density of the crystal affected by this defect?
Answer:
Density of the crystal decreases.

(iii) What type of ionic substances show such defect?
Answer:
Crystals having
(a) high coordination number and
(b) ions (cations and anions) of almost similar sizes. For example: KCl, KBr.