NCERT MCQ CLASS-12 CHAPTER-13 | BIOLOGY NCERT MCQ | ORGANISMS AND POPULATION | EDUGROWN

In This Post we are  providing Chapter-13 Organisms and Population  NCERT MCQ for Class 12 Biology which will be beneficial for students. These solutions are updated according to 2021-22 syllabus. These MCQS  can be really helpful in the preparation of Board exams and will provide you with a brief knowledge of the chapter.

NCERT MCQ ON ORGANISMS AND POPULATION

Question 1.
The shifting of an organism temporarily from the stressful habitat to a more hospitable area and return when stressful period is over is called

(a) Suspend
(b) Migrate
(c) Hibernation
(d) Aestivation

Answer: (b) Migrate

Question 2.
Winter sleep is also called as

(a) Hibernation
(b) Suspend
(c) Migrate
(d) Aestivation

Answer: (a) Hibernation

Question 3.
To avoid summer-related problems –
heat and desiccation by organism is called
(a) Hibernation
(b) Suspend
(c) Migrate
(d) Aestivation

Answer: (d) Aestivation

Question 4.
A stage of suspended development is called

(a) Diapause
(b) Suspend
(c) Migrate
(d) Aestivation

Answer: (a) Diapause

Question 5.
Both the species benefit in

(a) Parasitism
(b) Mutualism
(c) Competition
(d) Predation

Answer: (b) Mutualism

Question 6.
Both species lose in

(a) Mutualism
(b) Competition
(c) Parasitism
(d) Predation

Answer: (b) Competition

Question 7.
One species benefit in

(a) Parasitism
(b) Predation
(c) Mutualism
(d) Both (a) and (b)

Answer: (d) Both (a) and (b)

Question 8.
The interaction where one species is benefitted and
the other is neither benefitted nor harmed is called
(a) Commensalism
(b) Amensalism
(c) Mutualism
(d) None of the above

Answer: (a) Commensalism

Question 9.
If one species is harmed whereas the other is unaffected is called

(a) Commensalism
(b) Amensalism
(c) Mutualism
(d) None of the above

Answer: (a) Commensalism

Question 10.
Parasites that feed on the external surface of the host organism are called

(a) Ecto parasites
(b) Endo parasites
(c) Brood parasitism
(d) None of the above

Answer: (a) Ecto parasites

Question 11.
Parasites that live inside the host body at different sites are called

(a) Ecto parasites
(b) Endo parasites
(c) Brood parasitism
(d) None of the above

Answer: (b) Endo parasites

Question 12.
The number of birth during a given period in the population that are added to the initial density is referred to

(a) Natality
(b) Mortality
(c) Sex-ratio
(d) None of the above

Answer: (a) Natality

Question 13.
The number of deaths in the population during a given period is referred to

(a) Natality
(b) Mortality
(c) Sex-ratio
(d) None of the above

Answer: (b) Mortality

Question 14.
The size of the population tells us a lot about its status in the
(a) Environment
(b) Sex-ratio
(c) Age pyramid
(d) Habitat

Answer: (d) Habitat

Question 15.
For human population, the age pyramids generally show age distribution of

(a) Only males
(b) Only females
(c) Of males and females
(d) None of the above

Answer: (c) Of males and females




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NCERT MCQ CLASS-12 CHAPTER-12 | BIOLOGY NCERT MCQ | BIOTECHNOLOGY AND ITS APPLICATION | EDUGROWN

In This Post we are  providing Chapter-12 Biotechnology and its Application  NCERT MCQ for Class 12 Biology which will be beneficial for students. These solutions are updated according to 2021-22 syllabus. These MCQS  can be really helpful in the preparation of Board exams and will provide you with a brief knowledge of the chapter.

NCERT MCQ ON BIOTECHNOGY AND ITS APPLICATION

1. Which of the following is commonly used as a vector for introducing a DNA fragment in human lymphocytes?

(a) X phage

(b) Retrovirus

(c) Ti plasmid

(d) PBR 322

Answer: B

2. Which kind of therapy was given in 1990 to a four year old girl with Adenosine Deaminase deficiency (ADA)?

(a) Gene therapy

(b) Chemo therapy

(c) Immunotherapy

(d) Radiation therapy

Answer: A

3. The two polypeptides of human insulin are linked together by________

(a) Phosphodiester bond

(b) Covalent bond

(c) Disulphide bridges

(d) Hydrogen bonds

Answer: C

4. Which part of the tobacco plant is infected bycMeloidogyne incognitia?

(a) Leaf

(b) Root

(c) Stem

(d) Flower

Answer: B

5. In Bt Cotton, the Bt toxin present in plant tissue as protoxin is converted into active toxin due to__________

(a) Alkaline PH of the insect gut

(b) Acidic pH of the insect gut

(c) Action of gut microorganism

(d) Presence of conversion factors in insect gut

Answer: A

6. The first human hormone produced by recombinant DNA technology is______

(a) Insulin

(b) Thyroxin

(c) Estrogen

(d) Progesterone

Answer:A

7. Which of the following Bt crops is being grown in India by the farmers?

(a) Brinjal

(b) Maize

(c) Soyabean

(d) Cotton

Answer: D

8. Tobacco plant resistant to a nematode have beencdeveloped by the introduction of DNA that produced in the host cells__________

(a) Both sense and anti-sense RNA

(b) A particular hormone

(c) An antifeedant

(d) A toxic protein

Answer: A

9. The first clinical gene therapy was given for treating__________

(a) Diabetes mellitus

(b) Chicken pox

(c) Rheumatoid arthritis 

(d) Adenosine Deaminase deficiency 

Answer: D

10. Which body of the Government of India regulates GM research and safety of introducing GM organisms for public services________

(a) Bio-safety committee

(b) Indian council for Agriculture Research

(c) Genetic engineering Approval Committee

(d) Research Committee on Genetic Manipulation.

Answer: C

11. Maximum number of existing transgenic animalsis of_________

(a) Fish

(b) Cow

(c) Pig

(d) Mice

Answer: D

12. Genetic engineering has been successfully used for producing:

(a) Transgenic mice for testing safety of polio vaccine before use in humans________

(b) Transgenic models for studying new treatments for certain cardiac diseases

(c) Transgenic cow – Rosie which produces high fat milk for making ghee

(d) Animals like bulls for farm work as they have super power

Answer: A

13. Transgenic animals are those which have________

(a) Foreign DNA in some of its cells

(b) Foreign DNA in all its cells

(c) Foreign RNA in all its cells 

(d) DNA and RNA both in the cells

Answer: B

14. Use of bioresources by multinational companies and organisations without authorisation from the concerned country and its people is called_______

(a) Biodegradation

(b) Bio-infringement

(c) Biopiracy

(d) Bioexploitation

Answer: C

15. The silencing of mRNA has been used in producing transgenic plants resistant to:

(a) Boll worms

(b) White rusts

(c) Nematodes

(d) Bacterial blights

Answer: C

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CLASS 12TH CHAPTER -2 Solutions |NCERT CHEMISTRY SOLUTIONS | EDUGROWN

NCERT Solutions for Class 12 Chemistry : The NCERT solutions provided here will enhance the concepts of the students, as well as suggest alternative methods to solve particular problems to the teachers. The target is to direct individuals towards problem solving strategies, rather than solving problems in one prescribed format. The links below provide the detailed solutions for all the Class 12 Chemistry problems.

Chemistry is much more than the language of Science. We have made sure that our solutions reflect the same. We aim to aid the students with answering the questions correctly, using logical approach and methodology. The NCERT Solutions provide ample material to enable students to form a good base with the fundamentals of the subject.

NCERT Solutions for Class 12 Chemistry Chapter : 2 Solutions

NCERT TEXTBOOK QUESTIONS SOLVED

2.1. Calculate the mass percentage of benzene (C6H6) and carbon tetrachloride (CCl4) if 22 g of benzene is dissolved in 122 g of carbon tetrachloride.
Ans: Mass of solution = Mass of C6H6 + Mass of CCl4
= 22 g+122 g= 144 g
Mass % of benzene = 22/144 x 100 =15.28 %
Mass % of CCl4 = 122/144 x 100 = 84.72 %

2.2. Calculate the mole fraction of benzene in solution containing 30% by mass in carbon tetrachloride.
Ans: 30% by mass of C6H6 in CCl4 => 30 g C6H6 in 100 g solution
.’. no. of moles of C6H6,(nC6h6) = 30/78 = 0.385
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Textbook Questions Q2

2.3. Calculate the molarity of each of the following solutions
(a) 30 g of Co(NO3)26H2O in 4·3 L of solution
(b) 30 mL of 0-5 M H2SO4 diluted to 500 mL.
Ans:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Textbook Questions Q3

2.4. Calculate the mass of urea (NH2CONH2) required in making 2.5 kg of 0.25 molal aqueous solution.
Ans: 0.25 Molal aqueous solution to urea means that
moles of urea = 0.25 mole
mass of solvent (NH2CONH2) = 60 g mol-1
.’. 0.25 mole of urea = 0.25 x 60=15g
Mass of solution = 1000+15 = 1015g = 1.015 kg
1.015 kg of urea solution contains 15g of urea
.’. 2.5 kg of solution contains urea =15/1.015 x 2.5 = 37 g

2.5. Calculate
(a) molality
(b) molarity and
(c) mole fraction of KI if the density of 20% (mass/mass) aqueous KI solution is 1·202 g mL-1.
Ans:
Step I. Calculation of molality of solution
Weight of KI in 100 g of the solution = 20 g
Weight of water in the solution = 100 – 20 = 80 g = 0-08 kg
Molar mass of KI = 39 + 127 = 166 g mol-1.
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Textbook Questions Q5
Step II. Calculation of molarity of solution
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Textbook Questions Q5.1
Step III. Calculation of mole fraction of Kl
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Textbook Questions Q5.2

2.6. HS, a toxic gas with rotten egg like smell, is used for the qualitative analysis. If the solubility of H2S in water at STP is 0.195 m, calculate Henry’s law constant.
Ans: Solubility of H2S gas = 0.195 m
= 0.195 mole in 1 kg of solvent
1 kg of solvent = 1000g
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Textbook Questions Q6

2.7. Henry’s law constant for CO2 in water is 1.67 x 10Pa at 298 K. Calculate the quantity of CO2 in 500 mL of soda water when packed under 2.5 atm CO2 pressure at 298 K.
Ans.:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Textbook Questions Q7

2.8 The vapour pressures of pure liquids A and B are 450 mm and 700 mm of Hg respectively at 350 K. Calculate the composition of the liquid mixture if total vapour pressure is 600 mm of Hg. Also find the composition in the vapour phase.
Ans:
Vapour pressure of pure liquid A (PA) = 450 mm
Vapour pressure of pure liquid B (PB) = 700 mm
Total vapour pressure of the solution (P) = 600 mm
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Textbook Questions Q8

2.9. Vapour pressure of pure water at 298 K is 23.8 m m Hg. 50 g of urea (NH2CONH2) is dissolved in 850 g of water. Calculate the vapour pressure of water for this solution and its relative lowering.
Ans:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Textbook Questions Q9

2.10. Boiling point of water at 750 mm Hg is 99.63°C. How much sucrose is to be added to 500 g of water such that it boils at 100°C.
Ans:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Textbook Questions Q10

2.11 Calculate the mass of ascorbic acid (vitamin C, C6H8O6) to be dissolved in 75 g of acetic acid to lower its melting point by 1·5°C. (Kf for CH3COOH) = 3·9 K kg mol-1)
Ans:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Textbook Questions Q11

2.12. Calculate the osmotic pressure in pascals exerted by a solution prepared by dissolving 1.0 g of polymer of molar mass 185,000 in 450 mL of water at 37°C.
Ans:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Textbook Questions Q12

NCERT EXERCISES

2.1. Define the terra solution. How many types of solutions are formed? Write briefly about each type with an example.
Sol: A solution is a homogeneous mixture of two or more chemically non-reacting substances. Types of solutions: There are nine types of solutions.
Types of Solution Examples
Gaseous solutions
(a) Gas in gas Air, mixture of 02 and N2, etc.
(b) Liquid in gas Water vapour
(c) Solid in gas Camphor vapours in N2 gas, smoke etc.
Liquid solutions
(a) Gas in liquid C02 dissolved in water (aerated water), and 02 dissolved in water, etc.
(b) Liquid in liquid Ethanol dissolved in water, etc.
(c) Solid in liquid Sugar dissolved in water, saline water, etc.
Solid solutions
(a) Gas in solid Solution of hydrogen in palladium
(b) Liquid in solid Amalgams, e.g., Na-Hg
(c) Solid in solid Gold ornaments (Cu/Ag with Au)

2.2. Suppose a solid solution is formed between two substances, one whose particles are very large and the other whose particles are very small. What type of solid solution is this likely to be ?
Sol: The solution likely to be formed is interstitial solid solution.

2.3 Define the following terms:
(i) Mole fraction
(ii) Molality
(iii) Molarity
(iv) Mass percentage
Sol: (i) Mole fraction: It is defined as the ratio of the number of moles of the solute to the total number of moles in the solution. If A is the number of moles of solute dissolved in B moles of solvent, then Mole fraction of solute
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q3
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q3.1
(ii) Molality: It is defined as die number of moles of a solute present in 1000g (1kg) of a solvent.
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q3.2
NOTE: Molality is considered better way of expressing concentration of solutions, as compared to molarity because molality does not change with change in temperature since the mass of solvent does not vary with temperature,
(iii) Molarity: It is defined as the number of moles of solute present in one litre of solution.
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q3.3
NOTE: Molarity is the most common way of expressing concentration of a solution in laboratory. However, it has one disadvantage. It changes with temperature because volume of a solution alters due to expansion and contraction of the liquid with temperature.
(iv) Mass percentage: It is the amount of solute in grams present in 100g of solution.
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q3.4

2.4. Concentrated nitric acid used in the laboratory work is 68% nitric acid by mass in aqueous solution. What should be the molarity of such a sample of acid if the density of the solution is 1·504 g mL-1 ?
Sol: Mass of HNO3 in solution = 68 g
Molar mass of HNO3 = 63 g mol-1
Mass of solution = 100 g
Density of solution = 1·504 g mL-1
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q4

2.5. A solution of glucose in water is labelled as 10% w/w, what would be the molality and mole fraction of each component in the solution? If the density of solution is 1 .2 g m L-1, then what shall be the molarity of the solution?
Sol: 10 percent w/w solution of glucose in water means 10g glucose and 90g of water.
Molar mass of glucose = 180g mol-1 and molar mass of water = 18g mol-1
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q5

NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q5.1

2.6. How many mL of 0.1 M HCl are required to react completely with 1 g mixture of Na2C0and NaHCOcontaining equimolar amounts of both?
Sol: Calculation of no. of moles of components in the mixture.
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q6

NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q6.1

2.7. Calculate the percentage composition in terms of mass of a solution obtained by mixing 300 g of a 25% and 400 g of a 40% solution by mass.
Sol:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q7

2.8. An antifreeze solution is prepared from 222.6 g of ethylene glycol, (CH6O) and200 g of water. Calculate the molality of the solution. If the density of the solution is 1.072 g mL-1, then what shall be the molarity of the solution?
Sol:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q8

NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q8.1

2.9. A sample of drinking water was found to be severely contaminated with chloroform (CHCl3), supposed to be a carcinogen. The level of contamination was 15 ppm (by mass).
(i) express this in percent by mass.
(ii) determine the molality of chloroform in the water sample.
Sol: 15 ppm means 15 parts in million (106) by mass in the solution.
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q9

2.10. What role does the molecular interaction play in solution of alcohol in water?
Sol: In case of alcohol as well as water, the molecules are interlinked by intermolecular hydrogen bonding. However, the hydrogen bonding is also present in the molecules of alcohol and water in the solution but it is comparatively less than both alcohol and water. As a result, the magnitude of attractive forces tends to decrease and the solution shows positive deviation from Raoult’s Law. This will lead to increase in vapour pressure of the solution and also decrease in its boiling point.

2.11. Why do gases always tend to be less soluble in liquids as the temperature is raised?
Sol: When gases are dissolved in water, it is accompanied by a release of heat energy, i.e., process is exothermic. When the temperature is increased, according to Lechatlier’s Principle, the equilibrium shifts in backward direction, and thus gases becomes less soluble in liquids.

2.12. State Henry’s law and mention some of its important applications.
Sol:
Henry’s law: The solubility of a gas in a liquid at a particular temperature is directly proportional to the pressure of the gas in equilibrium with the liquid at that temperature.
or
The partial pressure of a gas in vapour phase is proportional to the mole fraction of the gas (x) in the solution. p = KHX
where KH is Henry’s law constant.
Applications of Henry’s law :
(i) In order to increase the solubility of CO2 gas in soft drinks and soda water, the bottles are normally sealed under high pressure. Increase in pressure increases the solubility of a gas in a solvent according to Henry’s Law. If the bottle is opened by removing the stopper or seal, the pressure on the surface of the gas will suddenly decrease. This will cause a decrease in the solubility of the gas in the liquid i.e. water. As a result, it will rush out of the bottle producing a hissing noise or with a fiz.
(ii) As pointed above, oxygen to be used by deep sea divers is generally diluted with helium inorder to reduce or minimise the painfril effects during decompression.
(iii) As the partial pressure of oxygen in air is high, in lungs it combines with haemoglobin to form oxyhaemoglobin. In tissues, the partial pressure of oxygen is comparatively low. Therefore, oxyhaemoglobin releases oxygen in order to carry out cellular activities.

2.13. The partial pressure of ethane over a solution containing 6.56 × 10-3 g of ethane is 1 bar. If the solution contains 5.00 × 10-2 g of ethane, then what shall be the partial pressure of the gas?
Sol:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q13

2.14. According to Raoult’s law, what is meant by positive and negative deviaitions and how is the sign of ∆solH related to positive and negative deviations from Raoult’s law?
Sol: Solutions having vapour pressures more than that expected from Raoult’s law are said to exhibit positive deviation. In these solutions solvent – solute interactions are weaker and ∆solH is positive because stronger A – A or B – B interactions are replaced by weaker A – B interactions. Breaking of the stronger interactions requires more energy & less energy is released on formation of weaker interactions. So overall ∆sol H is positive. Similarly ∆solV is positive i.e. the volume of solution is some what more than sum of volumes of solvent and solute.
So there is expansion in volume on solution formation.
Similarly in case of solutions exhibiting negative deviations, A – B interactions are stronger than A-A&B-B. So weaker interactions are replaced by stronger interactions so , there is release of energy i.e. ∆sol H is negative.

2.15. An aqueous solution of 2 percent non-volatile solute exerts a pressure of 1·004 bar at the boiling point of the solvent. What is the molecular mass of the solute ?
Sol:
According to Raoult’s Law,
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q15

2.16  Heptane and octane form an ideal solution. At 373 K, the vapour pressures of the two liquid components are 105.2 kPa and 46.8 kPa respectively. What will be the vapour pressure of a mixture of 26.0 g of heptane and 35.0 g of octane?
Sol.
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q16

NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q16.1

2.17.  The vapour pressure of water is 12.3 kPa at 300 K. Calculate vapour pressure of 1 molal solution of a non-volatile solute in it
Sol: 1 molal solution of solute means 1 mole of solute in 1000g of the solvent.
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q17

2.18. Calculate the mass of a non-volatile solute (molecular mass 40 g mol-1) that should be dissolved in 114 g of octane to reduce its pressure to 80%. (C.B.S.E. Outside Delhi 2008)
Sol: According to Raoult’s Law,
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q18

2.19. A solution containing 30g of non-volatile solute exactly in 90 g of water has a vapour pressure of 2.8 kPa at 298 K. Further, 18g of water is then added to the solution and the new of vapour pressure becomes 2.9 kPa at 298 K. Calculate
(i) molar mass of the solute.
(ii) vapour pressure of water at 298 K.
Sol: Let the molar mass of solute = Mg mol-1
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q19

NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q19.1

NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q19.2

2.20. A 5% solution (by mass) of cane sugar in water has freezing point of 271 K. Calculate the freezing point of 5% glucose in water if freezing point of pure water is 273.15 K.
Sol: Mass of sugar in 5% (by mass) solution means 5gin 100g of solvent (water)
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q20

2.21. Two elements A and B form compounds having formula AB2 and AB4. When dissolved in 20g of benzene (C6H6), 1 g of AB2 lowers the freezing point by 2.3 K whereas 1.0 g of AB4 lowers it by 1.3 K. The molar depression constant for benzene is 5.1 K kg mol-1. Calculate atomic masses of A and B.
Sol:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q21

2.22. At 300 K, 36 g glucose present per litre in its solution has osmotic pressure of 4·98 bar. If the osmotic pressure of the solution is 1·52 bar at the same temperature, what would be its concentration?
Sol:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q22

NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q22.1

2.23. Suggest the most important type of intermolecular attractive interaction in the following pairs:
(i) n-hexane and n-octane
(ii) I2 and CCl4.
(iii) NaCl04 and water
(iv) methanol and acetone
(v) acetonitrile (CH3CN) and acetone (C3H60)
Sol: (i) Both w-hexane and n-octane are non-polar. Thus, the intermolecular interactions will be London dispersion forces.
(ii) Both I2 and CCl4 are non-polar. Thus, the intermolecular interactions will be London dispersion forces.
(iii) NaCl04 is an ionic compound and gives Na+ and Cl04 ions in the Solution. Water is a polar molecule. Thus, the intermolecular interactions will be ion-dipole interactions.
(iv) Both methanol and acetone are polar molecules. Thus, intermolecular interactions will be dipole-dipole interactions.
(v) Both CH3CN and C3H6O are polar molecules. Thus, intermolecular interactions will be dipole-dipole interactions.

2.24. Based on solute solvent interactions, arrange the following in order of increasing solubility in n-octane and explain. Cyclohexane, KCl, CH3OH, CH3CN.
Sol: n-octane (C8H18) is a non-polar liquid and solubility is governed by the principle that like dissolve like. Keeping this in view, the increasing order of solubility of different solutes is:
KCl < CH3OH < CH3C=N < C6H12 (cyclohexane).

2.25. Amongst the following compounds, identify which are insoluble, partially soluble and highly soluble in water?
(i) phenol
(ii) toluene
(iii) formic acid
(iv) ethylene glycol
(v) chloroform
(vi) pentanol
Sol: (i) Phenol (having polar – OH group) – Partially soluble.
(ii) Toluene (non-polar) – Insoluble.
(iii) Formic acid (form hydrogen bonds with water molecules) – Highly soluble.
(iv) Ethylene glycol (form hydrogen bonds with water molecules) Highly soluble.
(v) Chloroform (non-polar)- Insoluble.
(vi) Pentanol (having polar -OH) – Partially soluble.

2.26. If the density of lake water is 1·25 g mL-1, and it contains 92 g of Na+ ions per kg of water, calculate the molality of Na+ ions in the lake. (C.B.S.E. Outside Delhi 2008)
Sol:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q26

2.27. If the solubility product of CuS is 6 x 10-16, calculate the maximum molarity of CuS in aqueous solution.
Sol:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q27

2.28. Calculate the mass percentage of aspirin (C9H8O4 in acetonitrile (CH3CN) when 6.5g of CHO is dissolved in 450 g of CH3CN.
Solution:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions-28

2.29. Nalorphene (C19H21NO3), similar to morphine, is used to combat withdrawal symptoms in narcotic users. Dose of nalorphene generally given is 1.5 mg. Calculate the mass of 1.5 x 10-3 m aqueous solution required for the above dose.
Solution:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q29

2.30. Calculate the amount of benzoic acid (C5H5COOH) required for preparing 250 mL of 0· 15 M solution in methanol.
Solution:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q30

2.31. The depression in freezing point of water observed for the same amount of acetic acid, trichloroacetic acid and trifluoroacetic acid increases in the order given above. Explain briefly.
Solution:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions-31
Fluorine being more electronegative than chlorine has the highest electron withdrawing inductive effect. Thus, triflouroacetic acid is the strongest trichloroacetic acid is second most and acetic acid is the weakest acid due to absence of any electron withdrawing group. Thus, F3CCOOH ionizes to the largest extent while CH3COOH ionizes to minimum extent in water. Greater the extent of ionization greater is the depression in freezing point. Hence, the order of depression in freezing point will be CH3COOH < Cl3CCOOH < F3CCOOH.

2.32. Calculate the depression in the freezing point of water when 10g of CH3CH2CHClCOOH is added to 250g of water. Ka = 1.4 x 1o-3 Kg = 1.86 K kg mol-1.

Solution:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions-32
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions-32.1

2.33. 19.5g of CH2FCOOH is dissolved in 500g of water. The depression in the freezing point of water observed is 1.0°C. Calculate the van’s Hoff factor and dissociation constant of fluoroacetic acid.

Solution:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions-33

2.34. Vapour pressure of water at 293 K is 17·535 mm Hg. Calculate the vapour pressure of water at 293 K when 25 g of glucose is dissolved in 450 g of water.
Solution:
According to Raoult’s Law,
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q34

2.35. Henry’s law constant for the molality of methane in benzene at 298 K is 4.27 x 105 mm Hg. Calculate the solubility of methane in benzene at 298 K under 760 mm Hg.

Solution:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions-35

2.36. 100g of liquid A (molar mass 140 g mol-1) was dissolved in 1000g of liquid B (molar mass 180g mol-1). The vapour pressure of pure liquid B was found to be 500 torr. Calculate the vapour pressure of pure liquid A and its vapour pressure in the solution if the total vapour pressure of the solution is 475 torr.

Solution:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions-36

2.37. Vapour pressures of pure acetone and chloroform at 328 K are 741.8 mm Hg and 632.8 mm Hg respectively. Assuming that they form ideal solution over the entire range of composition, plot Ptotal, Pchlroform and Pacetone as a function of χacetone. The experimental data observed for different compositions of mixtures is:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions-37q
Plot this data also on the same graph paper. Indicate whether it has positive deviation or negative deviation from the ideal solution.

Solution:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions-37

2.38. Benzene and toluene form ideal solution over the entire range of composition. The vapour pressure of pure benzene and toluene at 300 K are 50.71 mm Hg and 32.06 mm Hg respectively. Calculate the mole fraction of benzene in vapour phase if 80g of benzene is mixed with 100g of toluene.

Solution:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions-38

2.39. The air is a mixture of a number of gases. The major components are oxygen and nitrogen with an approximate proportion of 20% is to 79% by volume at 298 K. The water is in equilibrium with air at a pressure of 10 atm. At 298 K if Henry’s law constants for oxygen and nitrogen are 3.30 x 107 mm and 6.51 x 107 mm respectively, calculate the composition of these gases in water.

Solution:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q39
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions-39.1

2.40. Determine the amount of CaCl2 (i = 2.47) dissolved in 2.5 litre of water such that its osmotic pressure is 0.75 atm at 27°C.

Solution:
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions-40
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions-40.1

2.41. Determine the osmotic pressure of a solution prepared by dissolving 25 mg of K2SO4 in 2 litre of water at 25°C, assuming that it is completely dissociated. (C.B.S.E. 2013)
Solution:
Step I. Calculation of Van’t Hoff factor (i)
K2SO4 dissociates in water as :
NCERT Solutions For Class 12 Chemistry Chapter 2 Solutions Exercises Q41

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CLASS 12TH CHAPTER -1 The Solid State |NCERT CHEMISTRY SOLUTIONS | EDUGROWN

NCERT Solutions for Class 12 Chemistry : The NCERT solutions provided here will enhance the concepts of the students, as well as suggest alternative methods to solve particular problems to the teachers. The target is to direct individuals towards problem solving strategies, rather than solving problems in one prescribed format. The links below provide the detailed solutions for all the Class 12 Chemistry problems.

Chemistry is much more than the language of Science. We have made sure that our solutions reflect the same. We aim to aid the students with answering the questions correctly, using logical approach and methodology. The NCERT Solutions provide ample material to enable students to form a good base with the fundamentals of the subject.

NCERT Solutions for Class 12 Chemistry Chapter : 1 Solid State

NCERT TEXTBOOK QUESTIONS SOLVED

1.1. Why are solids rigid?
Ans: The constituent particles in solids have fixed positions and can oscillate about their mean positions. Hence, they are rigid.

1.2. Why do solids have definite volume?
Ans: Solids keep their volume because of rigidity in their structure. The interparticle forces are very strong. Moreover, the interparticle spaces are very few and small as well. As a result, their volumes cannot change by applying pressure.

1.3. Classify the following as amorphous or crystalline solids: Polyurethane, naphthalene, benzoic acid, Teflon, potassium nitrate, cellophane, polyvinyl chloride, fibreglass, copper
Ans: Crystalline solids: Benzoic acid, potassium nitrate, copper Amorphous solids: Polyurethane, Teflon, cellophane, polyvinyl chloride, fibreglass

1.4. Why is glass considered as super cooled liquid ? (C.B.S.E. Delhi 2013)
Ans: Glass is considered to be super cooled liquid because it shows some of the characteristics of liquids, though it is an amorphous solid. For example, it is slightly thicker at the bottom. This can be possible only if it has flown like liquid, though very slowly.

1.5. Refractive index of a solid is observed to have the same value along all directions. Comment on the nature of this solid. Would it show cleavage property?
Ans: As the solid has same value of refractive index along all directions, it is isotropic in nature and hence amorphous. Being amorphous solid, it will not show a clean cleavage and when cut, it will break into pieces with irregular surfaces.

1.6. Classify the following solids in different categories based on the nature of the intermolecular forces: sodium sulphate, copper, benzene, urea, ammonia, water, zinc sulphide, diamond, rubedium, argon, silicon carbide.
Ans: Ionic, metallic, molecular, molecular, molecular (hydrogen-bonded), molecular (hydrogen-bonded), ionic, covalent, metallic, molecular, covalent (network).

1.7. Solid A is a very hard electrical insulator in. solid as well as in molten state and melts at extremely high temperature. What type of solid is it?
Ans: It is a covalent or network solid.

1.8. Why are ionic solids conducting in the molten state and not in the solid-state?
Ans: In the ionic solids, the electrical conductivity is due to the movement of the ions. Since the ionic mobility is negligible in the solid state, these are non-conducting in this state. Upon melting, the ions present acquire some mobility. Therefore, the ionic solids become conducting

1.9. What type of solids are electrical conductors, malleable and ductile?
Ans: Metallic solids

 1.10. Give the significance of a lattice point.
Ans: The lattice point denotes the position of a particular constituent in the crystal lattice. It may be atom, ion or a molecule. The arrangement of the lattice points in space is responsible for the shape of a particular crystalline solid.

1.11. Name the parameters that characterise a unit cell.
Ans: A unit cell is characterised by the following parameters:
(i)the dimensions of unit cell along three edges: a, b and c.
(ii)the angles between the edges: α (between b and c); β (between a and c) and γ (between a and b)

1.12. Distinguish between :
(i) Hexagonal and monoclinic unit cells
(ii) Face-centred and end-centred unit cells.
Ans:
(i) In a hexagonal unit cell :
a = b # c; α = β = 90° and γ = 120°
In a monoclinic unit cell :
a # b # c and α = γ = 90° and β # 90°
(ii) In a face-centered unit cell, constituent particles are located at all the corners as well as at the centres of all the faces.
In end-centered unit cell, constituent particles are located at all the corners as well as at the centres of two opposite faces. (C.B.S.E Foreign 2015)
NCERT Solutions For Class 12 Chemistry Chapter 1 The Solid State Textbook Questions Q12

NCERT Solutions For Class 12 Chemistry Chapter 1 The Solid State Textbook Questions Q12.1

1.13. Explain how many portions of an atom located at
(i)corner and (ii)body centre of a cubic unit cell is part of its neighbouring unit cell.
Ans: (i) An atom at the comer is shared by eight adjacent unit cells. Hence, portion of the atom at the comer that belongs to one unit cell=1/8.
(ii)An atom at the body centre is not shared by any other unit cell. Hence, it belongs fully to unit cell.

1.14. What is the two-dimensional coordination number of a molecule in a square close-packed layer?
Ans: In the two-dimensional square close-packed layer, a particular molecule is in contact with four molecules. Hence, the coordination number of the molecule is four.

1.15. A compound forms hexagonal close-packed. structure. What is the total number of voids in 0. 5 mol of it? How many of these are tetrahedral voids?
Ans:
No. of atoms in close packings 0.5 mol =0.5 x 6.022 x 1023 =3.011 x 1023
No. of octahedral voids = No. of atoms in packing =3.011 x 1023
No. of tetrahedral voids = 2 x No. of atoms in packing
= 2 x 3.011 x 1023 = 6.022 x 1023
Total no. of voids = 3.011 x 1023 + 6.022 x 1023
= 9.033 x 1023

1.16. A compound is formed by two elements M and N. The element N forms ccp and atoms of the element M occupy 1/3 of the tetrahedral voids. What is the formula of the compound? (C.B.S.E. Foreign 2015)
Ans: Let us suppose that,
the no. of atoms of N present in ccp = x
Since 1/3rd of the tetrahedral voids are occupied by the atoms of M, therefore,
the no. of tetrahedral voids occupied = 2x/3
The ratio of atoms of N and M in the compound = x : 2x/3 or 3 : 2
∴ The formula of the compound = N3M2 or M2N3

1.17. Wh ich of the following lattices has the highest packing efficiency (i) simple cubic (ii) body-centered cubic and (iii) hexagonal close-packed lattice?
Ans: Packing efficiency of:
Simple cubic = 52.4% bcc = 68% hcp = 74%
hcp lattice has the highest packing efficiency.

1.18. An element with molar mass 2:7 x 10-2 kg mol-1 forms a cubic unit cell with edge length 405 pm. If its density is 2:7 x 103 kg m-3, what is the nature of the cubic unit cell ? (C.B.S.E. Delhi 2015)
Ans: 
NCERT Solutions For Class 12 Chemistry Chapter 1 The Solid State Textbook Questions Q18
Since there are four atoms per unit cell, the cubic unit cell must be face centred (fcc) or cubic close packed (ccp).

1.19. What type of defect can arise when a solid is heated? Which physical property is affected by it and in what way?
Ans: When a solid is heated, vacancy defect is produced in the crystal. On heating, some atoms or ions leave the lattice site completely, i.e., lattice sites become vacant. As a result-of this defect, density of the substances decreases.

1.20. What types of stoichiometric defects are shown by (C.B.S.E. Delhi 2013)
(i) ZnS
(ii) AgBr?
Ans:
(i) ZnS crystals may show Frenkel defects since the cationic size is smaller as compared to anionic size.
(ii) AgBr crystals may show both Frenkel and Schottky defects.

1.21. Explain how vacancies are introduced in an ionic solid when a cation of higher valence is added as an impurity in it.
Ans: Let us take an example NaCl doped with SrCl, impurity when SrCl2 is added to NaCl solid as an impurity, two Na+ ions will be replaced and one of their sites will be occupied by Sr21- while the other will remain vacant. Thus, we can say that when a cation of higher valence is added as an impurity to an ionic solid, two or more cations of lower valency are replaced by a cation of higher valency to maintain electrical neutrality. Hence, some cationic vacancies are created.

1.22. Ionic solids, which have anionic vacancies due to metal excess defect, develop colour. Explain with the help of a suitable example.
Ans: Let us take an example of NaCl. When NaCl crystal is heated in presence of Na vapour, some Clions leave their lattice sites to combine with Na to form NaCl. The e-1 s lost by Na to form Na+ (Na+ + Cl—> NaCl) then diffuse into the crystal to occupy the anion vacancies. These sites are called F-centres. These e-s absorb energy from visible light, get excited to higher energy level and when they fall back to ground state, they impart yellow colour to NaCl crystal.

1.23. A group 14 element is to be converted into n-type semiconductor by doping it with a suitable impurity. To which group should this impurity belong?
Ans: Impurity from group 15 should be added to get n-type semiconductor.

1.24. What type of substances would make better permanent magnets, ferromagnetic or ferrimagnetic. Justify your answer.
Ans: Ferromagnetic substances make better permanent magnets. This is because when placed in magnetic field, their domains get oriented in the directions of magnetic field and a strong magnetic field is produced. This ordering of domains persists even when external magnetic field is removed. Hence, the ferromagnetic substance becomes a permanent magnet.

NCERT EXERCISES

1.1. Define the term ‘amorphous’. Give a few examples of amorphous solids.
Sol. Amorphous solids are those substances, in which there is no regular arrangement of its constituent particles, (i.e., ions, atoms or molecules). The arrangement of the constituting particles has only short-range order, i.e., a regular and periodically repeating pattern is observed over short distances only, e.g., glass, rubber, and plastics.

1.2. What makes glass different from a solid such as quartz? Under what conditions could quartz be converted into glass?
Sol. Glass is a supercooled liquid and an amorphous substance. Quartz is the crystalline form of silica (SiO2) in which tetrahedral units SiO4 are linked with each other in such a way that the oxygen atom of one tetrahedron is shared with another Si atom. Quartz can be converted into glass by melting it and cooling the melt very rapidly. In the glass, SiO4 tetrahedra are joined in a random manner.

1.3 Classify each of the following solids as ionic, metallic, modular, network (covalent), or amorphous:
(i) Tetra phosphorus decoxide (P4O10) (ii) Ammonium phosphate, (NH4)3PO4 (iii) SiC (iv) I2 (v) P(vii) Graphite (viii), Brass (ix) Rb (x) LiBr (xi) Si
Sol.
NCERT Solutions For Class 12 Chemistry Chapter 1 The Solid State Exercises Q3

1.4 (i) What is meant by the term ‘coordination number’?
(ii) What is the coordination number of atom
(a) in a cubic close-packed structure?
(b) in a body centred cubic structure?
Sol. (i) The number of nearest neighbours of a particle are called its coordination number.
(ii) (a) 12 (b) 8

1.5. How can you determine the atomic mass of an unknown metal if you know its density and dimensions of its unit cell ? Explain your answer. (C.B.S.E. Outside Delhi 2011)
Sol.
NCERT Solutions For Class 12 Chemistry Chapter 1 The Solid State Exercises Q5

NCERT Solutions For Class 12 Chemistry Chapter 1 The Solid State Exercises Q5.1

1.6 ‘Stability of a crystal is reflected in the magnitude of its melting points’. Comment. Collect melting points of solid water, ethyl alcohol, diethyl ether and methane from a data book. What can you say about the intermolecular forces between these molecules?
Sol. Higher the melting point, greater are the forces holding the constituent particles together and thus greater is the stability of a crystal. Melting points of given substances are following. Water = 273 K, Ethyl alcohol = 155.7 K, Diethylether = 156.8 K, Methane = 90.5 K.
The intermoleoilar forces present in case of water and ethyl alcohol are mainly due to the hydrogen bonding which is responsible for their high melting points. Hydrogen bonding is stronger in case of water than ethyl alcohol and hence water has higher melting point then ethyl alcohol. Dipole-dipole interactions are present in case of diethylether. The only forces present in case of methane is the weak van der Waal’s forces (or London dispersion forces).

1.7. How will you distinguish between the following pairs of terms :
(a) Hexagonal close packing and cubic close packing
(b) Crystal lattice and unit cell
(c) Tetrahedral void and octahedral void.
Sol.
(a) In hexagonal close packing (hcp), the spheres of the third layer are vertically above the spheres of the first layer
(ABABAB……. type). On the other hand, in cubic close packing (ccp), the spheres of the fourth layer are present above the spheres of the first layer (ABCABC…..type).
(b) Crystal lattice: It deplicts the actual shape as well as size of the constituent particles in the crystal. It is therefore, called space lattice or crystal lattice.
NCERT Solutions For Class 12 Chemistry Chapter 1 The Solid State Exercises Q7Unit cell: Each bricks represents the unit cell while the block is similar to the space or crystal lattice. Thus, a unit cell is the fundamental building block of the space lattice.
(c) Tetrahedral void: A tetrahedral void is formed when triangular void made by three spheres of a particular layer and touching each other.
NCERT Solutions For Class 12 Chemistry Chapter 1 The Solid State Exercises Q7.1
Octahedral void: An octahedral void or site is formed when three spheres arranged at the corners of an equilateral triangle are placed over anothet set of spheres.
NCERT Solutions For Class 12 Chemistry Chapter 1 The Solid State Exercises Q7.2

1.8 How many lattice points are there is one unit cell of each of the following lattices?
(i) Face centred cubic (if) Face centred tetragonal (iii) Body centred cubic
Sol.
NCERT Solutions For Class 12 Chemistry Chapter 1 The Solid State Exercises Q8

1.9 Explain:
(i) The basis of similarities and differences between metallic and ionic crystals.
(ii) Ionic solids are hard and brittle.
Sol. (i) Metallic and ionic crystals
Similarities:
(a) There is electrostatic force of attraction in both metallic and ionic crystals.
(b) Both have high melting points.
(c) Bonds are non-directional in both the cases.
Differences:
(a) Ionic crystals are bad conductors of electricity in solids state as ions are not free to move. They can conduct electricity only in die molten state or in aqueous solution. Metallic crystals are good conductors of electricity in solid state as electrons are free to move.
(b) Ionic bond is strong due to strong electrostatic forces of attraction.
Metallic bond may be strong or weak depending upon the number of valence electrons and the size of the kernels.
(ii) Ionic solids are hard and brittle.Ionic solids are hard due to the presence of strong electrostatic forces of attraction. The brittleness in ionic crystals is due to the non- directional bonds in them.

1.10 Calculate the efficiency of packing in case of a metal crystal for (i) simple cubic, (ii) body centred cubic, and (iii) face centred cubic (with the assumptions that atoms are touching each other).
Sol. Packing efficiency: It is the percentage of total space filled by the particles.
NCERT Solutions For Class 12 Chemistry Chapter 1 The Solid State Exercises Q10

NCERT Solutions For Class 12 Chemistry Chapter 1 The Solid State Exercises Q10.1

NCERT Solutions For Class 12 Chemistry Chapter 1 The Solid State Exercises Q10.2

1.11 Silver crystallises in fcc lattice. If edge length of the cell is 4.07 x 10-8 cm and density is 10.5 g cm-3, calculate the atomic mass of silver.
Sol.
NCERT Solutions For Class 12 Chemistry Chapter 1 The Solid State Exercises Q11

1.12. A cubic solid is made of two elements P and Q. Atoms Q are at the corners of the cube and P at the body centre. What is the formula of the compound ? What is the co-ordination number of P and Q?
Sol. Contribution by atoms Q present at the eight corners of the cube = 18= x 8 = 1
Contribution by atom P present at the body centre = 1
Thus, P and Q are present in the ratio 1:1.
∴ Formula of the compound is PQ.
Co-ordination number of atoms P and Q = 8.

1.13 Niobium crystallises in a body centred cubic structure. If density is 8.55 g cm-3, calculate atomic radius of niobium, using its atomic mass 93u.
Sol.
NCERT Solutions For Class 12 Chemistry Chapter 1 The Solid State Exercises Q13

1.14 If the radius of the octahedral void is r and radius of the atoms in close-packing is R, derive relation between rand R.
Sol. A sphere is fitted into the octahedral void as shown in the diagram.
NCERT Solutions For Class 12 Chemistry Chapter 1 The Solid State Exercises Q14

1.15 Copper crystallises into a fee lattice with edge length 3.61 x 10-8 cm. Show that the calculated density is in agreement with its measured value of 8.92 gcm-3.
Sol.
NCERT Solutions For Class 12 Chemistry Chapter 1 The Solid State Exercises Q15
This calculated value of density is closely in agreement with its measured value of 8.92 g cm3.

Question 16.
Analysis shows that nickel oxide has the formula Ni0.98 O1.00. What fractions of nickel exist as Ni2+ and Ni3+ ions?
Solution:
98 Ni-atoms are associated with 100 O – atoms. Out of 98 Ni-atoms, suppose Ni present as Ni2+ = x
Then Ni present as Ni3+ = 98 – x
Total charge on x Ni2+ and (98 – x) Ni3+ should
be equal to charge on 100 O2- ions.
Hence, x × 2 + (98 – x) × 3 = 100 × 2 or 2x + 294 – 3x = 200 or x = 94
∴ Fraction of Ni present as Ni2+ = 9498 × 100 = 96%
Fraction of Ni present as Ni3+ = 498 × 100 = 4%

Question 17.
What are semi-conductors? Describe the two main types of semiconductors and contrast their conduction mechanisms.
Solution:
Semi-conductors are the substances whose conductivity lies in between those of conductors and insulators. The two
main types of semiconductors are n-type and p-type.
(i) n-type semiconductor: When a silicon or germanium crystal is doped with group 15 element like P or As, the dopant atom forms four covalent bonds like Si or Ge atom but the fifth electron, not used in bonding, becomes delocalised and continues its share towards electrical conduction. Thus silicon or germanium doped with P or As is called H-type semiconductor, a-indicative of negative since it is the electron that conducts electricity.

(ii) p-type semiconductor: When a silicon or germanium is doped with group 13 element like B or Al, the dopant is present only with three valence electrons. An electron vacancy or a hole is created at the place of missing fourth electron. Here, this hole moves throughout the crystal like a positive charge giving rise to electrical conductivity. Thus Si or Ge doped with B or Al is called p-type semiconductor, p stands for positive hole, since it is the positive hole that is responsible for conduction.
NCERT Solutions For Class 12 Chemistry Chapter 1 The Solid State Exercises Q17

Question 18.
Non-stoichiometric cuprous oxide, Cu2O can be prepared in laboratory. In this oxide, copper to oxygen ratio is slightly less than 2:1. Can you account for the fact that this substance is a p-type semiconductor?
Solution:
The ratio less than 2 : 1 in Cu20 shows cuprous (Cu+) ions have been replaced by cupric (Cu2+) ions. For maintaining electrical neutrality, every two Cu+ ions will be replaced by one Cu2+ ion thereby creating a hole. As conduction will be due to the presence of these positive holes, hence it is a p-type semiconductor.

Question 19.
Ferric oxide crystallises in a hexagonal dose- packed array of oxide ions with two out of every three octahedral holes occupied by ferric ions. Derive the formula of the ferric oxide.
Solution:
Suppose the number of oxide ions (O2-) in the packing = 90
∴ Number of octahedral voids = 90
As 2/3rd of the octahedral voids are occupied by ferric ions, therefore, number of ferric ions 2 present = 23 × 90 = 60
∴ Ratio of Fe3+ : O2- = 60 : 90 = 2 : 3
Hence, the formula of ferric oxide is Fe2O3.

Question 20.
Classify each of the following as being either a p-type or n-type semiconductor :

  1. Ge doped with In
  2. B doped with Si.

Solution:

  1. Ge is group 14 element and In is group 13 element. Hence, an electron deficient hole is created and therefore, it is a p – type semiconductor.
  2. B is group 13 element and Si is group 14 element, there will be a free electron, So, it is an n-type semiconductor.

Question 21.
Gold (atomic radius = 0.144 nm) crystallises in a face centred unit cell. What is the length of the side of the unit cell ?
Solution:
For a face centred cubic unit cell (fcc)
Edge length (a) = 22–√r = 2 x 1.4142 x 0.144 mm = 0.407 nm

Question 22.
In terms of band theory, what is the difference

  1. between a conductor and an insulator
  2. between a conductor and a semiconductor?

Solution:
In most of the solids and in many insulating solids conduction takes place due to migration of electrons under the influence of electric field. However, in ionic solids, it is the ions that are responsible for the conducting behaviour due to their movement.

(i) In metals, conductivity strongly depends upon the number of valence electrons available in an atom. The atomic orbitals of metal atoms form molecular orbitals which are so close in energy to each other, as to form a band. If this band is partially filled or it overlaps with the higher energy unoccupied conduction band, then electrons can flow easily under an applied electric field and the metal behaves as a conductor.
NCERT Solutions for Class 12 Chemistry Chapter 1 The Solid State 20

If the gap between valence band and next higher unoccupied conduction band is large, electrons cannot jump into it and such a substance behaves as insulator.

(ii) If the gap between the valence band and conduction band is small, some electrons may jump from valence band to the conduction band. Such a substance shows some conductivity and it behaves as a semiconductor. Electrical conductivity of semiconductors increases with increase in temperature, since more electrons can jump to the conduction band. Silicon and germanium show this type of behaviour and are called intrinsic semiconductors. Conductors have no forbidden band.

Question 23.
Explain the following terms with suitable examples :

  1. Schottky defect
  2. Frenkel defect
  3. Interstitial defect
  4. F-centres.

Solution:
(i) Schottky defect : In Schottky defect a pair of vacancies or holes exist in the crystal lattice due to the absence of equal number of cations and anions from their lattice points. It is a common defect in ionic compounds of high coordination number where both cations and anions are of the same size, e.g., KCl, NaCl, KBr, etc. Due to this defect density of crystal decreases and it begins to conduct electricity to a smaller extent.

(ii) Frenkel defect : This defect arises when some of the ions in the lattice occupy interstitial sites leaving lattice sites vacant. This defect is generally found in ionic crystals where anion is much larger in size than the cation, e.g., AgBr, ZnS, etc. Due to this defect density does not change, electrical conductivity increases to a small extent and there is no change in overall chemical composition of the crystal.
NCERT Solutions for Class 12 Chemistry Chapter 1 The Solid State 21

(iii) Interstitial defect : When some constituent particles (atoms or molecules) occupy an interstitial site of the crystal, it is said to have interstitial defect. Due to this defect the density of the substance increases.

(iv) F-Centres : These are the anionic sites occupied by unpaired electrons. F-centres impart colour to crystals. The colour results by the excitation of electrons when they absorb energy from the visible light falling on the crystal.

Question 24.
Aluminium crystallises in a cubic close packed structure. Its metallic radius is 125 pm.

  1. What is the length of the side of the unit cell?
  2. How many unit cells are there in 1.00 cm3 of aluminium?

Solution:
NCERT Solutions for Class 12 Chemistry Chapter 1 The Solid State 22

Question 25.
If NaCI is doped with 10-3 mol % SrCl2, what is the concentration of cation vacancies?
Solution:
Let moles of NaCI = 100
∴ Moles of SrCl2 doped = 10-3
Each Sr2+ will replace two Na+ ions. To maintain electrical neutrality it occupies one position and thus creates one cation vacancy.
∴ Moles of cation vacancy in 100 moles NaCI = 10-3
Moles of cation vacancy in one mole
NaCI = 10-3 × 10-2 = 10-5
∴ Number of cation vacancies
= 10-5 × 6.022 × 1023 = 6.022 × 1018 mol-1

Question 26.
Explain the following with suitable example:

  1. Ferromagnetism
  2. Paramagnetism
  3. Ferrimagnetism
  4. Antiferromagnetism
  5. 12-16 and 13-15 group compounds.

Solution:
(i) Ferromagnetic substances : Substances which are attracted very strongly by a magnetic field are called ferromagnetic substances, e.g., Fe, Ni, Co and CrO2 show ferromagnetism. Such substances remain permanently magnetised, once they have been magnetised. This type of magnetic moments are due to unpaired electrons in the same direction.
NCERT Solutions for Class 12 Chemistry Chapter 1 The Solid State 23
The ferromagnetic material, CrO2, is used to make magnetic tapes used for audio recording.

(ii) Paramagnetic substances : Substances which are weakly attracted by the external magnetic field are called paramagnetic substances. The property thus exhibited is called paramagnetism. They are magnetised in the same direction as that of the applied field. This property is shown by those substances whose atoms, ions or molecules contain unpaired electrons, e.g., O2, Cu2+, Fe3+, etc. These substances, however, lose their magnetism in the absence of the magnetic field.

(iii) Ferrimagnetic substances : Substances which are expected to possess large magnetism on the basis of the unpaired electrons but actually have small net magnetic moment are called ferrimagnetic substances, e.g., Fe3O4, ferrites of the formula M2+Fe2O4 where M = Mg, Cu, Zn, etc. Ferrimagnetism arises due to the unequal number of magnetic moments in opposite direction resulting in some net magnetic moment.
NCERT Solutions for Class 12 Chemistry Chapter 1 The Solid State 24

(iv) Antiferromagnetic substances : Substances which are expected to possess paramagnetism or ferromagnetism on the basis of unpaired electrons but actually they possess zero net magnetic moment are called antiferromagnetic substances, e.g., MnO. Antiferromagnetism is due to the presence of equal number of magnetic moments in the opposite directions
NCERT Solutions for Class 12 Chemistry Chapter 1 The Solid State 25

(v) 13-15 group compounds : When the solid state materials are produced by combination of elements of groups 13 and 15, the compounds thus obtained are called 13-15 compounds. For example, InSb, AlP, GaAs, etc.

12-16 group compounds : Combination of elements of groups 12 and 16 yield some solid compounds which are referred to as 12-16 compounds. For example, ZnS, CdS, CdSe, HgTe, etc. In these compounds, the bonds have ionic character.

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Class 12th Chapter -15 Communication Systems |NCERT Physics Solutions | Edugrown

NCERT Solutions for Class 12 Physics Chapter – 15 Communications Systems includes all the important topics with detailed explanation that aims to help students to understand the concepts better. Students who are preparing for their Class 12 exams must go through NCERT Solutions for Class 12 Physics Chapter 15 Communications Systems. Going through the solutions provided on this page will help you to know how to approach and solve the problems.

Students can also find NCERT intext, exercises and back of chapter questions. Also working on Class 12 Physics Chapter 15 NCERT Solutions will be most helpful to the students to solve their Home works and Assignments on time.

NCERT Solutions for Class 12 Physics Chapter : 15 Communications Systems

NCERT Exercises

Question 1.
Which of the following frequencies will be suit-able for beyond-the-horizon communication using sky waves?
(a) 10 kHz
(b) 10 MHz
(c) 1 GHz
(d) 1000 GHz
Solution:
(b) : 10 MHz will be suitable frequency for sky waves as lower frequency of 10 kHz will require large radiating antenna and higher frequencies 1 GHz and 1000 GHz will pass through the ionosphere and will not be reflected by it.

Question 2.
Frequencies in the UHF range normally propagate by means of:
(a) Ground waves
(b) Sky waves
(c) Surface waves
(d) Space waves
Solution:
(d) : Frequencies in the UHF range normally propagates by means of space waves. The high frequency space waves are ideal for frequency modulation but do not bend with ground.

Question 3.
Digital signals
(i) do not provide a continuous set of values,
(ii) represent values as discrete steps,
(iii) can utilize binary system, and
(iv) can utilize decimal as well as binary systems.

Which of the above statements are true?

(a) (i) and (ii) only
(b) (ii) and (iii) only
(c) (i), (ii) and (iii) but not (iv)
(d) All of (i), (ii), (iii) and (iv).
Solution:
(c) : Decimal system represents a continuous set of values which cannot be utilized by digital signals.

Question 4.
Is it necessary for a transmitting antenna to be at the same height as that of the receiving antenna for the line of sight communication? A TV transmitting antenna is 81 m tall. How much service area can it cover if the receiving antenna is at the ground level?
Solution:
No, for line of sight communication, the two antenna may not be at the same height. Surface area
A=\pi { d }^{ 2 }=\pi \left( 2hR \right) =\cfrac { 22 }{ 7 } \times 2\times 81\times 6.4\times { 10 }^{ 6 }
=3258.5\times { 10 }^{ 6 }sq.metre=3258.5sq.km

Question 5.
A carrier wave of peak voltage 12 V is used to transmit a message signal. What should be the peak voltage of the modulating signal in order to have a modulation index of 75%?
Solution:
Modulation index, \mu =\cfrac { { A }_{ m } }{ { A }_{ c } } so, peak voltage
{ A }_{ m }={ \mu A }_{ c }=0.75\times 12=9V

Question 6.
A modulating signal is a square wave, as shown in Figure
NCERT Solutions for Class 12 Physics Chapter 15 Communication Systems 1
The carrier wave is given by c(t) = 2sin (8πt) volts
(i) Sketch the amplitude modulated wave form
(ii) What is the modulation index?
Solution:
(i) The amplitude modulated wave is shown here’:
NCERT Solutions for Class 12 Physics Chapter 15 Communication Systems 2
(ii) Modulation index, \mu \cfrac { { A }_{ m } }{ { A }_{ c } } =\cfrac { 1V }{ 2V } =0.5

Question 7.
For an amplitude modulated wave, the maximum amplitude is found to be 10 V while the minimum amplitude is found to be 2 V. Determine the modulation index, p. What would be the value of p if the minimum amplitude is zero volt?
Solution:
We know
Modulation index, \mu =\cfrac { { A }_{ m } }{ { A }_{ c } }
Also, minimum amplitude, { A }_{ min }={ A }_{ c }\left( 1-\mu \right)
Maximum amplitude, { A }_{ max }={ A }_{ c }\left( 1+\mu \right)
So, modulation index, \mu =\cfrac { { A }_{ max }{ -A }_{ min } }{ { A }_{ max }{ +A }_{ min } }
or \mu =\cfrac { 10-2 }{ 10+2 } =\cfrac { 8 }{ 12 } =2/3=0.67
if Amin = O, then modulation index, \cfrac { { A }_{ mix }-{ A }_{ min } }{ { A }_{ mix }+{ A }_{ min } } =\cfrac { 10-0 }{ 10+0 } =\cfrac { 10 }{ 10 } =1

Question 8.
Due to economic reasons, only the upper side band of an AM wave is transmitted, but at the receiving station, there is a facility for generating the carrier. Show that if a device is available which can multiply two signals, then it is possible to recover the modulating signal at the receiver station.
Solution:
Let, the received signal be cos(ωc + ωm)t The carrier signal available at the receiving station is Ac cos ωct Multiplying the two signals, we get A1Ac cos  (ωc + ωm)t cos ωc\cfrac { { A }_{ 1 }{ A }_{ c } }{ 2 } \left[ cos\left( 2{ \omega }_{ c }+{ \omega }_{ m } \right) t+cos{ \omega }_{ m }t \right] If this signal is passed through a low pass filter, we can recover the modulating signal \cfrac { { A }_{ 1 }{ A }_{ c } }{ 2 } cos{ \omega }_{ m }t

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Class 12th Chapter -14 Semiconductor Electronics: Materials, Devices and Simple Circuits |NCERT Physics Solutions | Edugrown

NCERT Solutions for Class 12 Physics Chapter – 14 Semiconductor Eectronics: Materials and Simple Circuits includes all the important topics with detailed explanation that aims to help students to understand the concepts better. Students who are preparing for their Class 12 exams must go through NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Eectronics: Materials and Simple Circuits. Going through the solutions provided on this page will help you to know how to approach and solve the problems.

Students can also find NCERT intext, exercises and back of chapter questions. Also working on Class 12 Physics Chapter 14 NCERT Solutions will be most helpful to the students to solve their Home works and Assignments on time.

NCERT Solutions for Class 12 Physics Chapter : 14 Semiconductor Eectronics: Materials and Simple Circuits

NCERT Exercises

Question 1.
in an n-type silicon, which of the following statement is true?
(a) Electrons are majority carriers and trivalent atoms are the dopants.
(b) Electrons are minority carriers and pentavalent atoms are the dopants.
(c) Holes are minority carriers and pentavalent atoms are the dopants.
(d) Holes are majority carriers and trivalent atoms are the dopants.
Solution:
(c) For n-type silicon statement (c) is true.

Question 2.
Which of the statements given in previous question is true for p-type semiconductors?
Solution:
(d) For p-type semiconductors statement (d) is true.

Question 3.
Carbon, silicon and germanium have four valence electrons each.These are characterised by valence and conduction bands separated by energy band gap respectively equal to (Eg)c’ (Eg)si and (Eg)Ge. Which of the following statements is true?
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 01
Solution:
(c) : The energy band gap is largest for carbon, less for silicon and least for germanium. So, the correct statement is (c).
(Eg)c > (Eg)si > (Eg)Ge

Question 4.
In an unbiased p-n junction, holes diffuse from the p-region to n-region because
(a) free electrons in the n-region attract them.
(b) they move across the junction by the potential difference.
(c) hole concentration in p-region is more as compared to n-region.
(d) all of the above.
Solution:
(c) : In the unbiased p-n junction, holes diffuse from the p-region to n-region because holes concentration in the p-region is high as compared to n-region.

Question 5.
When a forward bias is applied to a p-n junction, it
(a) raises the potential barrier.
(b) reduces the majority carrier current to zero.
(c) lowers the potential barrier.
(d) none of the above
Solution:
(c) : Under forward biasing the move¬ment of majority charge carriers across the junction reduces the width of depletion layer or lowers the potential barrier.

Question 6.
For transistor action, which of the following statements is/are correct:
(a) Base, emitter and collector regions should have similar size and doping concentrations.
(b) The base region must be very thin and lightly doped.
(c) The emitter junction is forward biased and collector junction is reverse biased.
(d) Both the emitter junction as well as the collector junction are forward biased.
Solution:
(b, c) For a transistor circuit in action, statements (b) and (c) are correct.

Question 7.
For a transistor amplifier, the voltage gain
(a) remains constant for all frequencies.
(b) is high at high and low frequencies and constant in the middle frequency range.
(c) is low at high and low frequencies and constant at mid frequencies.
(d) none of the above.
Solution:
(c) : The voltage gain in a transistor as amplifier is low at high and low frequencies and constant at mid frequencies.

Question 8.
In half-wave rectification, what is the output frequency if the input frequency is 50 Hz. What is the output frequency of a full-wave- rectifier for the same input frequency?
Solution:
In half wave rectification, only one ripple is obtained per cycle in the output.
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 2
Output frequency of a half wave rectifier = input frequency = 50 Hz In full wave rectification, two ripples are obtained per cycle in the output.
Output frequency = 2 × input frequency = 2 × 50 = 100 Hz
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 3

Question 9.
For a CE-transistor amplifier, the audio signal voltage across the collector resistance of 2 kΩ is 2 V. Suppose the current amplification factor of the transistor is 100, find the input signal voltage and base current, if the base resistance is 1 kΩ
Solution:
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 4
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 5

Question 10.
Two amplifiers are connected one after the other in series (cascaded). The first amplifier has a voltage gain of 10 and the second has a voltage gain of 20. If the input signal is 0. 01 volt, calculate the output ac signal.
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 6
Solution:
Total voltage gain can be calculated as
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 7
Question 11.
A p-n photo diode is fabricated from a semiconductor with band gap of 2.8 eV. Can it detect a wavelength of 6000 nm?
Solution:
Energy of the incident photon with a band gap of 6000 nm.
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 8
The photo diode need an energy of 2.8 eV to give response to incident light. As E < Eg, the given photo diode cannot detect the radiation of wavelength 6000 nm.
Question 12.
The number of silicon atoms per m3 is 5 × 1028. This is doped simultaneously with 5 × 1022 atoms per m3 of Arsenic and 5 × 1020 per m3 atoms of Indium. Calculate the number of electrons and holes. Given that n, = 1.5 × 1016 m3. Is the material n-type or p-type?
Solution:
We know that for each atom doped of Arsenic, one free electron is received. Similarly, for each atom doped of indium, a vacancy is created. So, the number of free electrons introduced by pentavalent impurity added ne = NAs = 5 × 1022 m-3
The number of holes introduced by trivalent impurity added
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 9
Question 13.
In an intrinsic semiconductor the energy gap Eg is 1.2 eV. Its hole mobility is much smaller than electron mobility and independent of temperature. What is the ratio between conductivity at 600 K and that at 300 K? Assume that the temperature dependence of intrinsic carrier concentration n, is given by
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 10
Solution:
Conductivity is given by σ = e (ne μe +nh μh) For intrinsic semiconductor ne = nh = ni Also mobility of holes (p,,) « mobility of electrons (pj So, conductivity a = enepe „ Temperature dependence of intrinsic carrier concentration
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 11
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 12
Conductivity increases rapidly with the rise of temperature.

Question 14.
In a p-n junction diode, the current I can be
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 13
is called the reverse saturation current, V is the voltage across the diode and is positive for forward bias and negative for reverse bias, and I is the current through the diode, kB is the Boltzmann constant (8.6 × 10-5 eV/K) and T is the absolute temperature. If for a given diode I0 = 5 × 10-12 A and T= 300 K, then
(a) What will be the forward current at a forward voltage of 0.6 V?
(b) What will be the increase in the current if the voltage across the diode is increased to 0.7 V?
(c) What is the dynamic resistance?
(d) What will be the current if reverse bias voltage changes from 1 V to 2 V?
Solution:
The current I through a junction diode is given as
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 14
(a) When V = 0.6 V
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 15
(b) When V = 0.7 V,
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 16
(c)
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 17
(d) For both the voltages, the current I will be almost equal to I0, showing almost infinite dynamic resistance in the reverse bias. I=-I0= – 5 × 10-12 A.

Question 15.
YOU are given the two circuits as shown in figure. Show that circuit (a) acts as OR gate while the circuit (b) acts as AND gate.
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 18
Solution:
Let us first find the Boolean expression for logic circuit (a)
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 19
By De-Morgan’s theorem we know
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 20
so, above logic circuit provides output as AND gate

Question 16.
Write the truth table for a NAND gate connected as given in following figure.
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 21
Hence identify the exact logic operation carried out by this circuit.
Solution:
The Boolean expression for NAND gate will be
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 22
Question 17.
You are given two circuits as shown in figure which consist of NAND gates. Identify the logic operation carried out by the two circuits.
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 23
Solution:
(a) Let us find Boolean expression for given logic circuit
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 24
(b) By De-Morgan’s theorem
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 25
so, the given logic circuit acts as OR gate.

Question 18.
Write the truth table for circuit given in figure below consisting of NOR gates and identify the logic operation (OR, AND, NOT) which this circuit is performing.
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 26
(Hint: A – 0, B = 1 then A and B inputs of second NOR gate will be 0 and hence Y = 1. Similarly work out the values of Yfor other combinations of A and B. Compare with the truth table of OR, AND, NOT gates and find the correct one.)
Solution:
Let us find the Boolean expression for the logic circuit.
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 27
Hence, the output of given logic circuit shows that logic circuit act as OR gate. Truth Table
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 28
Question 19.
Write the truth table for the circuits given in figure consisting of NOR gates only. Identify the logic operations (OR, AND, NOT) performed by the two circuits.
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 29
Solution:
Boolean expression for logic circuit (a)
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 30
Here the given NOR gate with short circuit input is acting as NOT gate. Its truth table is
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 31
Boolean expression for logic circuit (b)
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 32
Hence, the logic circuit acts like AND gate. Its truth table is
NCERT Solutions for Class 12 Physics Chapter 14 Semiconductor Electronics Materials, Devices and Simple Circuits 33

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Class 12th Chapter -13 Nuclei |NCERT Physics Solutions | Edugrown

NCERT Solutions for Class 12 Physics Chapter – 13 Nuclei includes all the important topics with detailed explanation that aims to help students to understand the concepts better. Students who are preparing for their Class 12 exams must go through NCERT Solutions for Class 12 Physics Chapter 13 Nuclei. Going through the solutions provided on this page will help you to know how to approach and solve the problems.

Students can also find NCERT intext, exercises and back of chapter questions. Also working on Class 12 Physics Chapter 13 NCERT Solutions will be most helpful to the students to solve their Home works and Assignments on time.

NCERT Solutions for Class 12 Physics Chapter : 13 Nuclei

Question 1.
(a) Two stable isotopes of lithium _{ 3 }^{ 6 }{ Li } and _{ 7 }^{ 3 }{ Li } have respective abundances of 7.5% and 92.5%. These isotopes have masses 6.01512 u and 7.01600 u respectively. Find the atomic mass of lithium.
(b) Boron has two stable isotope.s, _{ 5 }^{ 10 }{ B } and _{ 5 }^{ 11 }{ B } Their respective masses are 10.01294 u and 11.00931 u, and the atomic mass of boron is
10.811 u. Find the abundances of _{ 5 }^{ 10 }{ B } and _{ 5 }^{ 11 }{ B }.
Solution:
Abundance of _{ 3 }^{ 6 }{ Li } is 7.5% and abundance
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 1
(b) Let abundance of _{ 5 }^{ 10 }{ B } x% than abundance of _{ 5 }^{ 11 }{ B } will be (100 – x)%.
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 2
Question 2.
The three stable isotopes of neon : _{ 10 }^{ 20 }Ne_{ 10 }^{ 21 }Ne and have respective abundances of 90.51%, 0.27% and 9.22%. The atomic masses of the three isotopes are 19.99 u, 20.99 u and 21.99 u, respectively. Obtain the average atomic mass of neon.
Solution:
Average atomic mass of neon with the given abundances,
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 3
Question 3.
Obtain the binding energy (in MeV) of a nitrogen nucleus \left( _{ 7 }^{ 14 }{ N } \right), given m \left( _{ 7 }^{ 14 }{ N } \right) = 14.00307 u
Solution:
The nucleus contains 7 protons and 
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 4
Question 4.
Obtain the binding energy of the nuclei _{ 26 }^{ 56 }{ Fe } and _{ 83 }^{ 209 }{ Bi } in units of MeV from the following data:
m\left( _{ 26 }^{ 56 }{ Fe } \right) = 55.934939 u
m\left( _{ 83 }^{ 209 }{ Bi } \right) = 208.980388 u
Solution:
Let us first find the binding energy of
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 5
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 6
Question 5.
A given coin has a mass of 3.0 g. Calculate the nuclear energy that would be required to separate all the neutrons and protons from each other. For simplicity assume that the
coin is entirely made of _{ 29 }^{ 63 }{ Cu } atoms (of mass 62.92960 u).
Solution:
Let us first find the B.E. of each copper nucleus and then we can find binding energy
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 7
Question 6.
Write nuclear reaction equations for
(i) a-decay of _{ 88 }^{ 226 }{ Ra }
(ii) a-decay of _{ 94 }^{ 242 }{ Pu }
(iii) p-decay of _{ 15 }^{ 32 }{ P }
(iv) p-decay of _{ 83 }^{ 210 }{ Bi }
(v) p+-decay of _{ 6 }^{ 11 }{ C }
(vi) p+-decay of _{ 43 }^{ 97 }{ Tc }
(vii) Electron capture of _{ 54 }^{ 120 }{ Xe }
Solution:
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 8
Question 7.
A radioactive isotope has a half-life of T years. How long will it take the activity to reduce to
(a) 3.125%
(b) 1% of its original value?
Required time, as cannot be solved by direct calculation as in part (a).
Solution:
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 9
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 10
Required time, as cannot be solved by direct calculation as in part (a)
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 11
Question 8.
The normal activity of living carbon-containing matter is found to be about 15 decays per minute for every gram of carbon. This activity arises from the small proportion of radioactive _{ 6 }^{ 14 }{ C } present with the stable carbon isotope _{ 6 }^{ 12 }{ C }. When the organism is dead, its interaction with the atmosphere (which maintains the above equilibrium activity) ceases and its activity begins to drop. From the known half-life (5730 years) of _{ 6 }^{ 14 }{ C }, and the measured activity, the age of the specimen can be approximately estimated. This is the principle of _{ 6 }^{ 14 }{ C } dating used in archaeology. Suppose a specimen from Mohenjodaro gives an activity of 9 decays per minute per gram of carbon. Estimate the approximate age of the Indus-Valley civilization.
Solution:
In order to estimate age, let us first find the activity ratio in form of time ‘t’. Given normal activity, R0 = 15 decays min-1 Present activity, R = 9 decays min-1, Tin = 5730 years Since activity is proportional to the number of radioactive atoms, therefore,
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 12
Question 9.
Obtain the amount of _{ 27 }^{ 16 }{ Co } necessary to provide a radioactive source of 8.0 mCi strength. The half-life of _{ 27 }^{ 16 }{ Co } is 5.3 years.
Solution:
Here rate of disintegration required
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 13
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 14
As 1 mole i.e., 60 g of cobalt contains 6.023 × 1023 atoms, so, the mass of cobalt required for given rate of disintegration
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 15
Question 10.
The half-life of _{ 38 }^{ 90 }{ Sr } is 28 years. What is the disintegration rate of 15 mg of this isotope?
Solution:
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 16
Question 11.
Obtain approximately the ratio of the nuclear radii of the gold isotope _{ 79 }^{ 197 }{ Au } and the silver isotope _{ 47 }^{ 107 }{ Au }.
Solution:
We know the radius of nucleus depend upon mass number ‘A’
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 17
Question 12.
Find the Q-value and the kinetic energy of the emitted a-particle in the a-decay of
(a) _{ 88 }^{ 226 }{ Ra } and (b) _{ 86 }^{ 220 }{ Rn }.
Given m\left( _{ 88 }^{ 226 }{ Ra } \right) = 226.02540 u,
m\left( _{ 86 }^{ 222 }{ Rn } \right) = 222.01750 u,
m\left( _{ 86 }^{ 220 }{ Rn } \right) = 220.01137 u,
m\left( _{ 84 }^{ 216 }{ Po } \right) = 216.00189 u, and
mx = 4.00260 u.
Solution:
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 18
Question 13.
The radionuclide “C decays according to _{ 6 }^{ 11 }{ C }\rightarrow _{ 5 }^{ 11 }{ B } + e+ + v: T1/2 = 20.3 min
The maximum energy of the emitted positron is 0.960 MeV.
Given the mass values:
m\left( _{ 6 }^{ 11 }{ C } \right) = 11.011434 u
m\left( _{ 5 }^{ 11 }{ B } \right) = 11.009305 u
Calculate Q and compare it with the maximum energy of the positron emitted.
Solution:
The given equation
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 19
As we know that different positrons comes out with different possible energies shared between daughter nucleus and positron.
So, the Q value of reaction is almost same as the maximum energy of positron emitted.

Question 14.
The nucleus _{ 10 }^{ 23 }{ Ne } decays by β emission. Write t down the β– decay equation and determine
r the maximum kinetic energy of the electrons emitted. Given that:
m\left( _{ 10 }^{ 23 }{ Ne } \right) = 22.994466 amu,
m\left( _{ 11 }^{ 23 }{ Na } \right) = 22.989770 amu.
Solution:
The β decay of _{ 10 }^{ 23 }{ Ne } may be explained as
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 20
As _{ 11 }^{ 23 }{ Na } is massive, the kinetic energy released is mainly shared by electron-positron pair. When the neutrino carries no energy, the electron has a maximum kinetic energy equal to 4.374 MeV.

Question 15.
The Q value of a nuclear reaction A + b—>C+d is defined by Q = [mA + mb-mc– md] c2, where the masses refer to the respective nuclei, Determine from the given data the Q-value of the following reactions and state whether the reactions are exothermic or endothermic.
(i) _{ 1 }^{ 1 }{ H }+_{ 1 }^{ 3 }{ H }\rightarrow _{ 1 }^{ 2 }{ H }+_{ 1 }^{ 2 }{ H }
(ii) _{ 6 }^{ 12 }{ C }+_{ 6 }^{ 12 }{ C }\rightarrow _{ 10 }^{ 20 }{ C }+_{ 2 }^{ 4 }{ C }
Atomic masses are given to be
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 21
Solution:
(i) Let us find the Q value in given first equation,
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 22
Negative Q value shows that reaction is endothermic.
(ii) Q value in the given second equation
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 23
Positive Q shows that the reaction is exothermic.

Question 16.
Suppose, we think of fission of a _{ 26 }^{ 56 }{ Fe } nucleus into two equal fragments, _{ 13 }^{ 28 }{ AI }. IS the fission energetically possible? Argue by working out Q of the process.
Given, m\left( _{ 26 }^{ 56 }{ Fe } \right) = 55.93494 u
and m\left( _{ 13 }^{ 28 }{ Ai } \right) = 27.98191 u.
Solution:
The fission of Fe-56 into two fragments of
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 24
As the Q-value is negative, the fission is not possible energycally.

Question 17.
The fission properties of _{ 94 }^{ 239 }{ Pu } are very similar to those of _{ 92 }^{ 235 }{ U }. The average energy released per fission is 180 MeV. How much energy, in MeV, is released if all the atoms in 1 kg of pure _{ 94 }^{ 239 }{ Pu } undergo fission?
Solution:
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 25
Question 18.
A 1000 MW fission reactor consumes half of its fuel in 5.00 y. How much _{ 92 }^{ 235 }{ U } did it contain initially? Assume that the reactor operates 80% of the time and that all the energy generated arises from the fission of _{ 92 }^{ 235 }{ U }and that this nuclide is consumed by the fission process.
Solution:
In the fission of one nucleus of _{ 92 }^{ 235 }{ U }, energy generated is 200 MeV.
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 26
Question 19.
How long can an electric lamp of 100 W be kept glowing by fusion of 2.0 kg of deuterium? Take the fusion reaction as
_{ 1 }^{ 2 }{ H }+_{ 1 }^{ 2 }{ H }\rightarrow _{ 2 }^{ 3 }{ He }+n+3.27MeV
Solution:
Number of atoms present in 2 g of deuterium = 6.023 × 1023 Total number of atoms present in 2000 g of deuterium
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 27
Energy released in the fusion of 2 deuterium atoms = 3.27 MeV
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 28
Question 20.
Calculate the height of potential barrier for a head-on collision of two deuterons. The effective radius of deuteron can be taken to be 2fm.
Solution:
For head on collision, distance between centers of two deuterons
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 29
This is a measure of height of coulomb barrier.

Question 21.

From the relation R = R0 A1/3, where R2 is a constant and A is the mass number of a nucleus, show that the nuclear matter density is nearly constant (i.e., independent of A).
Solution:
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 30
As R is constant, p is contact so, nuclear density is constant irrespective of mass number or size.

Question 22.
For the β+ (positron) emission from a nucleus, there is another competing process known as electron capture (electron from an inner orbit, say, the /(-shell, is captured by the nucleus and a neutrino is emitted).
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 31
Show that if β+ emission is energetically allowed, electron capture is necessarily allowed but not vice-versa.
Solution:
Let us first consider positron emission.
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 32
This mean if Q1 > 0 then Q2 > 0 but vice vesa is not necessarily allowed. So, electron capture is not necessary for positron emission.

Question 23.
In a periodic table the average atomic mass of magnesium is given as 24.312 u. The average value is based on their relative natural abundance on earth. The three isotopes and their masses are _{ 12 }^{ 24 }{ Mg } (23.98504 u), _{ 12 }^{ 25 }{ Mg } (24.98584 u) and _{ 12 }^{ 26 }{ Mg } (25.98259 u).The natural abundance of _{ 12 }^{ 24 }{ Mg } 78.99% by mass. Calculate the abundances of the other two isotopes.
Solution:
Let the abundance of isotope _{ 12 }^{ 26 }{ Mg } is
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 33

Question 24.
The neutron separation energy is defined as the energy required to remove a neutron from the nucleus. Obtain the neutron separation energies of the nuclei _{ 20 }^{ 41 }{ Ca } and _{ 13 }^{ 27 }{ Ai } from
the following data:
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 34
Solution:
Neutron separation of _{ 20 }^{ 40 }{ Ca } can be obtained as E = Energy equivalent of total mass afterward – Energy equivalent of nucleus before
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 35
Question 25.
A source contains two phosphorus radio -nuclides _{ 15 }^{ 32 }{ P } (T1/2 = 14.3 days) and _{ 15 }^{ 33 }{ P } (Tv2 = 25.3 days). Initially, 10% of the decays come from _{ 15 }^{ 32 }{ P } How long one must wait until 90% do so?
Solution:
In the mixture of P-32 and P-33 initially 10% decay came from P-33. Hence initially 90% of the mixture is P-32 and 10% of the mixture is P-33. Let after time’t’ the mixture is left with 10% of P-32 and 90% of P-33. Half life of both P-32 and P-33 are given as 14.3 days and 25.3 days respectively. Let V be total mass undecayed initially and ‘y’ be total mass undecayed finally. Let initial number of P-32 nuclides = 0.9 x Final number of P-32 nuclides = 0.1 y Similarly, initial number of P-33 nuclides = 0.l x Final number of P-33 nuclides = 0.9 y For isotope P-32
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 36
Question 26.
Under certain circumstances, a nucleus can decay by emitting a particle more massive than an a-partide. Consider the following decay processes:
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 37
Calculate the Q-values for these decays and determine that both are energetically allowed.
Solution:
Let us calculate Q value for the given decay process. For first decay process
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 38
Since, Q value is positive in both the cases, hence decay process in both ways are possible

Question 27.
Consider the fission of _{ 92 }^{ 238 }{ U } by fast neutrons. In one fission event, no neutrons are emitted and the final end products, after the beta decay of the primary fragments are _{ 58 }^{ 140 }{ Ce } and _{ 15 }^{ 32 }{ Ru }. Calculate Qfor this fission process. The relevant atomic and particle masses are:
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 39
Solution:
The fission of U-238 by fast neutrons into fragments Ce-140 and Ru-99 with energy released Q can be written as
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 40
Question 28.
Consider the D-T reaction (deuterium – tritium fusion)
_{ 1 }^{ 2 }{ H }+_{ 1 }^{ 3 }{ H }\rightarrow _{ 2 }^{ 4 }{ He }+n
(a) Calculate the energy released in MeV in this reaction from the data
(_{ 1 }^{ 2 }{ H }) = 2.014102 u, m (_{ 1 }^{ 3 }{ H }) = 3.016049 u
(b) Consider the radius of both deuterium and tritium to be approximately 2.0 fm. What is the kinetic energy needed to overcome the coulomb repulsion between the two nuclei? To what temperature must the gases be heated to initiate the reaction?
Solution:
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 41
Classically, K.E. atleast equal to this amount is required to overcome Coulomb repulsion. Using the relation
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 42
Question 29.
Obtain the maximum kinetic energy of β-particles and the radiation frequencies of y-decays in the decay scheme shown in figure. You are given that
m\left( _{ 79 }^{ 198 }{ Au } \right) = 197.968233 u, m\left( _{ 80 }^{ 198 }{ Ag } \right) = 197.966760 u
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 43
Solution:
Energy corresponding to y1
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 44
Question 30.
Calculate and compare the energy released by
(a) fusion of 1.0 kg of hydrogen deep within the Sun and
(b) the fission of 1.0 kg of 235U in a fission reactor.
Solution:
(a) In the fusion reactions taking place within core of sun, 4 hydrogen nuclei combines to form a helium nucleus with the release of 26 MeV of energy.
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 45
(b) Energy released per fission of U-235 is 200 MeV.
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 46
So the energy released in fusion of 1 kg of Hydrogen is nearly 8 times the energy released in fission of 1 kg of uranium-235.

Question 31.
Suppose India has a target of producing by 2020 AD, 200,000 MW of electric power, ten percent of which is to be obtained from nuclear power plants. Suppose we are given that, on an average, the efficiency of utilization (/.e., conversion to electric energy) of thermal energy produced in a reactor was 25%. How much amount of fissionable uranium would our country need per year? Take the heat energy per fission of 235U to be about 200 MeV.
Solution:
10% of total power 200,000 MW to be obtained from nuclear power plant by 2020 AD.
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 47
NCERT Solutions for Class 12 Physics Chapter 13 Nucle 48
Hence mass of uranium needed per year = 3.08 × 104 kg

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Class 12th Chapter -12 Atoms |NCERT Physics Solutions | Edugrown

NCERT Solutions for Class 12 Physics Chapter – 12 Atoms includes all the important topics with detailed explanation that aims to help students to understand the concepts better. Students who are preparing for their Class 12 exams must go through NCERT Solutions for Class 12 Physics Chapter 12 Atoms. Going through the solutions provided on this page will help you to know how to approach and solve the problems.

Students can also find NCERT intext, exercises and back of chapter questions. Also working on Class 12 Physics Chapter 12 NCERT Solutions will be most helpful to the students to solve their Home works and Assignments on time.

NCERT Solutions for Class 12 Physics Chapter : 12 Atoms

NCERT Exercises

Question 1.
Choose the correct alternative from the clues given at the end of each statement:
(a) The size of the atom in Thomson’s model is _____ the atomic size in Rutherford’s model. (Much greater than / no different from / much less than).
(b) In the ground state of _____ electrons are in stable equilibrium, while in _____ electrons always experience a net force. (Thomson’s model / Rutherford’s model).
(c) A classical atom based on _____ is doomed to collapse. (Thomson’s model / Rutherford’s model)
(d) An atom has a nearly continuous mass distribution in a _____ but has a highly non-uniform mass distribution in _____ (Thomson’s model / Rutherford’s model).
(e) The positively charged part of the atom possesses most of the mass in _____ (Rutherford’s model / both the models).
Solution:
(a) not different from
(b) Thomson’s model, Rutherford’s model
(c) Rutherford’s model
(d) Thomson’s model, Rutherford’s model
(e) both the models

Question 2.
Suppose you are given a chance to repeat the alpha-particle scattering experiment using a thin sheet of solid hydrogen in place of the gold foil. (Hydrogen is a solid at temperatures below 14 K). What results do you expect?
Solution:
The nucleus of a hydrogen atom is a proton. The mass of a proton is 1.67 × 10-27 kg, whereas the mass of an incident a-particle is 6.64 × 10-27 kg. Because the incident a-particles are more massive than the target nuclei (protons), the a-particle won’t bounce back even in a head on collision. It is similar to a football colliding with a tennis ball at rest. Thus, there would be no appreciable scattering.

Question 3.
What is the shortest wavelength present in the Paschen series of spectral lines?
Solution:
For shortest wavelength of Paschen series, n1 = 3, n2 = ∞
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 1
Question 4.
A difference of 2.3 eV separates two energy levels in an atom. What is the frequency of radiation emitted when the atom makes a transition from the upper level to the lower level?
Solution:
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 2
Question 5.
The ground state energy of hydrogen atom is -13.6 eV. What are the kinetic and potential energies of the electron in this state?
Solution:
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 3
Question 6.
A hydrogen atom initially in the ground level absorbs a photon, which excites it to the n = 4 level. Determine the wavelength and frequency of photon.
Solution:
Energy of an electron in the nth orbit of
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 4
Question 7.
(a) Using the Bohr’s model, calculate the speed of the electron in a hydrogen atom in the n = 1, 2 and 3 levels,
(b) Calculate the orbital period in each of these levels.
Solution:
(a) Speed of the electron in Bohr’s nth orbit is
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 5
(b) Orbital period of electron in Bohr’s first orbit is
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 6
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 7
Question 8.
The radius of the innermost electron orbit of a hydrogen atom is 5.3 × 10-11 m. What are the radii of the n = 2andn = 3 orbits?
Solution:
Radius of innermost electron
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 8
Question 9.
A 12.5 eV electron beam is used to bombard gaseous hydrogen at room temperature. What series of wavelengths will be emitted?
Solution:
In ground state, energy of gaseous hydrogen at room temperature=-13.6 eV. When it is bombarded with 12.5 eV electron beam, the energy becomes – 13.6 + 12.5 = – 1.1 eV. The electron would jump from n = 1 to n = 3, 13 6 where E3 = \cfrac { 13.6 }{ 3^{ 3 } } = -1.5 eV. On de-excitation the electron may jump from n = 3 to n = 2 giving rise to Balmer series. It may also jump from n = 3 to n = 1, giving rise to Lyman series.

Question 10.
ln accordance with the Bohr’s model, find the quantum number that characterises the earth’s revolution around the sun in an orbit of radius 1.5 × 1011 m with orbital speed 3 × 104 m s-1. (Mass of earth = 6.0 × 10224kg)
Solution:
According to Bohr’s quantization condition of angular momentum, Angular momentum of the earth around the sun,
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 9
Question 11.
Answer the following questions, which helpyou understand the difference between Thomson’s model and Rutherford’s model better.
(a) Is the average angle of deflection of a-particles by a thin gold foil predicted by Thomson’s model much less, about the same, or much greater than that predicted by Rutherford’s model?
(b) Is the probability of backward scattering (i.e., scattering of a-particles at angles greater than 90°) predicted by Thomson’s model much less, about the same, or much greater than that predicted by Rutherford’s model?
(c) Keeping other factors fixed, it is found experimentally that for small thickness t, the number of a-particles scattered at moderate angles is proportional to What clue does this linear dependence on f provide?
(d) In which model is it completely wrong to ignore multiple scattering for the calculation of average angle of scattering of a-particles by a thin foil?
Solution:
(a) Nearly the same. This is because we are considering the average angle of deflection.
(b) Much less, because there is no such massive core (nucleus) in Thomson’s model as in Rutherford’s model.
(c) This suggests that scattering is mainly due to a single collision, because the chance of a single collision increases linearly with the number of the target atoms, and hence linearly with the thickness of the foil.
(d) In Thomson model, positive charge is distributed uniformly in the atom. So single collision causes very little deflection. The observed average scattering angle can be explained only by considering multiple scattering. Hence, it is wrong to ignore multiple scattering in Thomson’s model.

Question 12.
The gravitational attraction between electron and proton in a hydrogen atom is weaker than the coulomb attraction by a factor of about 10-40. An alternative way of looking at this fact is to estimate the radius of the first Bohr orbit of a hydrogen atom if the electron and proton were bound by gravitational attraction. You will find the answer interesting.
Solution:
The radius of the first orbit in Bohr’s model is calculated by considering the electrostatic force between electrons and proton in nucleus.
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 10
This radius is much greater than the estimated size of the whole universe.

Question 13.
Obtain an expression for the frequency of radiation emitted when a hydrogen atom de-excites from level n to level (n – 1). For large n, show that this frequency equals the classical frequency of revolution of the electron in the orbit.
Solution:
Let us first find the frequency of revolution of electron in the orbit classically. In Bohr’s model velocity of electron in nth
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 11
Now, let us find the frequency of radiation emitted when a hydrogen atom de-excites from level h to level (n – 1).
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 12
Equation (i) and (ii) are equal, hence for large value of n, the classical frequency of revolution of electron in nth orbit is same as frequency of radiation when electron de-excite from level n to(n – l).

Question 14.
Classically, an electron can be in any orbit around the nucleus of an atom. Then what determines the typical atomic size? Why is an atom not, say, thousand times bigger than its typical size? The question had greatly puzzled Bohr before he arrived at his famous model of the atom that you have learnt in the text. To simulate what he might well have done before his discovery, let us play as follows with the basic constants of nature and see if we can get a quantity with the dimensions of length that is roughly equal to the known size of an atom 10 10 m)
(a) Construct a quantity with the dimensions of length from the fundamental constants e, me, and c. Determine its numerical value.
(b) You will find that the length obtained in (a) is many orders of magnitude smaller than the atomic dimensions. Further, it involves c. But energies of atoms are mostly in non-relativistic domain where c is not expected to play any role. This is what may have suggested Bohrto discard c and look for ‘something else’ to get the right atomic size. Now, the Planck’s constant h had already made its appearance elsewhere. Bohr’s great insight lay in recognising that h, me, and e will yield the right atomic size. Construct a quantity with the dimension of length from h, me, and e and confirm that its numerical value has indeed the correct order of magnitude.
Solution:
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 13
(b) A quantity with the dimension of length from h, me and e
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 114
The length is of the order of atomic size (10-10m)
Question 15.
The total energy of an electron in the first excited state of the hydrogen atom is about – 3.4 eV.
(a) What is the kinetic energy of the electron in this state?
(b) What is the potential energy of the electron in this state?
(c) Which of the answers above would change if the choice of the zero of potential energy is changed?
Solution:
Kinetic energy of an electron in an orbit,
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 15
(a) Kinetic energy of electron in this state E = -K
(b) Potential energy E = U/2, U = 2E = 2 (-3.4) = -6.8 eV
(c)
 If thg zero of the potential energy is chosen differently, the kinetic energy remain the same. Although potential energy and hence total energy changes.

Question 16.
If Bohr’s quantisation postulate (angular momentum = nh/2n) is a basic law of nature, it should be equally valid for the case of planetary motion also. Why then do we never speak of quantisation of orbits of planets around the sun?
Solution:
Angular momentum mvr = n \cfrac { h }{ 2\pi } associated with planetary motion are incomparably large relative to h. For example angular momentum of earth in its orbital motion is of the order of 1070 \cfrac { h }{ 2\pi }.
For such large value of n, the difference in successive energies and angular momenta of the quantised levels of the Bohr model are so small that one can predict the energy level continuous.

Question 17.
Obtain the first Bohr’s radius and the ground state energy of a muonic hydrogen atom [/.e., an atom in which a negatively charged muon (μ) of mass about 207 me orbits around a proton].
Solution:
In Bohr’s model, the radius of nth orbit,
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 16
In the given muonic hydrogen atom, a negatively charged muon (μ) of mass 207 me revolve around a proton. Therefore radius of electron and muon can be written as
NCERT Solutions for Class 12 Physics Chapter 12 Atoms 17

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Class 12th Chapter -11 Dual Nature of Radiation and Matter |NCERT Physics Solutions | Edugrown

NCERT Solutions for Class 12 Physics Chapter – 11 Dual Nature of Radiation and Matter includes all the important topics with detailed explanation that aims to help students to understand the concepts better. Students who are preparing for their Class 12 exams must go through NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter. Going through the solutions provided on this page will help you to know how to approach and solve the problems.

Students can also find NCERT intext, exercises and back of chapter questions. Also working on Class 12 Physics Chapter 11 NCERT Solutions will be most helpful to the students to solve their Home works and Assignments on time.

NCERT Solutions for Class 12 Physics Chapter : 11 Dual Nature of Radiation and Matter

NCERT Exercises

Question 1.
Find the:
(a) maximum frequency, and
(b) minimum wavelength of X-rays produced by 30 kV electrons.
Solution:
(a) Maximum energy of X-ray photon = Maximum energy of an accelerated electron
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 1
Question 2.
The work function of caesium metal is 2.14 eV. When light of frequency 6 × 1014 Hz is incident on the metal surface, photo emission of electrons occurs. What is the:
(a) maximum kinetic energy of the emitted electrons,
(b) stopping potential, and
(c) maximum speed of the emitted photo-electrons?
Solution:
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 2
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 3
Question 3.
The photoelectric cut-off voltage in a certain experiment is 1.5 V. What is the maximum kinetic energy of photo electrons emitted?
Solution:
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 4
Question 4.
Monochromatic light of wavelength 632.8 nm is produced by a helium-neon laser. The power emitted is 9.42 mW.
(a) Find the energy and momentum of each photon in the light beam.
(b) How many photons per second, on the average, arrive at a target irradiated by this beam? (Assume the beam to have uniform cross-section which is less than the target area)
(c) How fast does a hydrogen atom have to travel in order to have the same momentum as that of the photon?
Solution:
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 5
(a) Energy of each photon,
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 6
(b) Number of photons arriving per second at the target,
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 7
(c) As mv = p
∴ Velocity, \upsilon =\frac { p }{ m } =\frac { 6.63\times 10^{ -27 }kgms^{ -1 } }{ 1.67\times 10^{ -27 }kg }
= 0.63 m s-1

Question 5.
The energy flux of sunlight reaching the surface of the earth is 1.388 × 103. How many photons (nearly) per square metre are incident on the earth per second? Assume that the photons in the sunlight have an average wavelength of 550 nm.
Solution:
Energy of each photon,
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 8
Number of photons incident on earth’s surface per second per square metre
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 9

Question 6.
In an experiment on photoelectric effect, the slope of the cut-off voltage versus frequency of incident light is found to be 4.12 × 10-15 V s. Calculate the value of Planck’s constant.
Solution:
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 10
Question 7.
A 100 W sodium lamp radiates energy uniformly in all directions. The lamp is located at the centre of a large sphere that absorbs all the sodium light which is incident on it. The wavelength of the sodium light is 589 nm.
(a) What is the energy per photon associated with the sodium light?
(b) At what rate are the photons delivered to the sphere?
Solution:
Here P = 100 W, λ = 589 nm = 589 × 10-9 m
(a) Energy of each photon,
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 11
(b) Rate at which photons are delivered to sphere,
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 12
Question 8.
The threshold frequency for a certain metal is 3.3 × 1014 Hz. If light of frequency 8.2 x 1014 Hz is incident on the metal, predict the cut off voltage for the photoelectric emission.
Solution:
According to Einstein’s relation
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 13
Question 9.
The work function for a certain metal is 4.2 eV. Will this metal give photoelectric emission for incident radiation of wavelength 330 nm?
Solution:
Let us calculate the energy associated with photons incident
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 14
Since, energy of incident photons i.e., 3.77 eV is less than work function, hence no emission will take place.

Question 10.
Light of frequency 7.21 × 1014 Hz is incident on a,metal surface. Electrons with a maximum speed of 6.0 × 105 m s-1 are ejected from the surface. What is the threshold frequency for photo emission of electrons?
Solution:
According to Einstein’s equation
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 15
Question 11.
Light of wavelength 488 nm is produced by an argon laser which is used in the photoelectric r effect. When light from this spectral line is incident on the emitter, the stopping (cut-off) potential of photo electrons is 0.38 V. Find the work function of the material from which the r emitter is made,
Solution:
Energy of incident radiation
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 16
Question 12.
Calculate the
(a) momentum, and
(b) de Broglie wavelength of the electrons accelerated through a potential difference of 56 V.
Solution:
An electron which is accelerated through a potential difference of 56 V will have kinetic energy K = 56 eV
(a) Momentum associated with accelerated electron
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 17
(b) Wavelength of electron accelerated
\lambda =\frac { h }{ p } =\frac { 6.63\times 10^{ -34 } }{ 4.04\times 10^{ -24 } } =0.164 nm

Question 13.
What is the
(a) momentum,
(b) speed, and
(c) de Broglie wavelength of an electron with kinetic energy of 120 eV.
Solution:
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 18
(a) Momentum of electron,
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 19
(b) Speed of electron
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 20
(c) de-Broglie wavelength associated with electron
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 21
Question 14.
The wavelength of light from the spectral emission line of sodium is 589 nm. Find the kinetic energy at which
(a) an electron, and
(b) a neutron, would have the same de Broglie wavelength.
Solution:
(a) Kinetic energy required by electron to have de-Broglie wavelength of 589 nm
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 22
(b) Kinetic energy of neutron to have de- Broglie wavelength of 589 nm
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 23
Question 15.
What is the de Broglie wavelength of
(a) a bullet of mass 0.040 kg travelling at the speed of 1.0 km s-1
(b) a ball of mass 0.060 kg moving at a speed of 1.0 ms-1, and
(c) a dust particle of mass 1.0 × 10-9 kg drifting with a speed of 2.2 m s-1?
Solution:
de Broglie wavelength \lambda =\cfrac { h }{ mv }
(a) Wavelength associated with bullet
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 24
(b) Wavelength associated with ball
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 25
(c) Wavelength associated with dust particle
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 26
Question 16.
An electron and a photon each have a wavelength of 1.00 nm. Find
(a) their momenta,
(b) the energy of the photon, and
(c) the kinetic energy of electron.
Solution:
(a) Momentum for both electron and photon will be same for same wavelength.
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 27
Question 17.
(a) For what kinetic energy of a neutron will the associated de Broglie wavelength be 1.40 × 10-10 m?
(b) Also find the de Broglie wavelength of a neutron, in thermal equilibrium with matter having an average kinetic energy
Solution:
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 28
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 29

Question 18.
Show that the wavelength of electromagnetic radiation is equal to the de Broglie wavelength of its quantum (photon).
Solution:
For a photon, de Broglie wavelength, \lambda =\cfrac { h }{ p } .
For an electromagnetic radiation of frequency u and wavelength λ'(= c/v), Momentum,
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 30
Thus the wavelength of the electromagnetic radiation is the same as the de Broglie wavelength of the photon.

Question 19.
What is the de Broglie wavelength of a nitrogen molecule in air at 300 K? Assume that the molecule is moving with the root-mean-square speed of molecules at this temperature. (Atomic mass of nitrogen = 14.0076 u, K = t. 38 × 10-23 J K-1).
Solution:
Let us first calculate mass of each N2 molecule.
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 31
Question 20.
(a) Estimate the speed with which electrons emitted from a heated cathode of an evacuated tube impinge on the anode maintained at a potential difference of 500 V with respect to the cathode. Ignore the small initial speeds of the electrons. The ‘specific charge’ of the electron i.e., its e/m is given to be 1.76 × 1011 C kg-1.
(b) Use the same formula you employ in (a) to obtain electron speed for an anode potential of 10 MV. Do you see what is wrong? In what way is the formula to be modified?
Solution:
(a) Energy of accelerated electron
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 32
This speed of electron is impossible. Since nothing can move with a speed greater than speed of light (c = 3 × 1o8 m s-1 The formula for kinetic energy E = 1/2 mv2 valid only for v « c. For the situation when speed v is comparable to speed of light c, we use relativistic formula. The relativistic mass is given by
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 33
Substituting the values
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 34

Question 21.
(a) A monoenergetic electron beam with electron speed of 5.20 × 106 m s-1 is subjected to a magnetic field of 1.30 × 10-4 T, normal to the beam velocity. What is the radius of the circle traced by the beam, given e/m for electron equals 1.76 × 1011 C
kg-1.
(b) Is the formula you employ in (a) valid for calculating radius of the path of a 20 MeV electron beam? If not, in what way is it modified?
Solution:
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 35
The normal magnetic field provides necessary centripetal force to the electron beam so that it can follow a circular path. Thus Force on an electron = Centripetal force due to magnetic field on an electron
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 36
The formula for radius of circular path is not valid at very high energies because such high energy
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 37
Question 22.
An electron gun with its collector at a potential of 100 V fires out electrons in a spherical bulb containing hydrogen gas at low pressure (10-2 mm of Hg). A magnetic field of 2.83 × 10-4 T curves the path of the electrons in a circular orbit of radius 12.0 cm. Determine e/m from the data.
Solution:
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 38

Question 23.
(a) An X-ray tube produces a continuous spectrum of radiation with its short wavelength end at 0.45 A. What is the maximum energy of a photon in the radiation?
(b) From your answer to (a), guess what order of accelerating voltage (for electrons) is required in such a tube ?
Solution:
(a) Minimum wavelength corresponds to maximum energy photons.
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 39
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 40
(b) In order to emit photons from the surface of energy 27.6 keV, the incident electrons striking on surface should have higher energy i.e., of the order of 30 keV.

Question 24.
In an accelerator experiment on high energy collisions of electrons with positrons, a certain event is interpreted as annihilation of an electron positron pair of total energy 10.2 BeV into two y-rays of equal energy. What is the wavelength associated with each y-ray? (1 BeV = 109 eV).
Solution:
In the process of annihilation, the total energy of electron-positron pair is shared equally by both y ray photons produced. Energy of two y-rays = Energy of electron- positron pair = 10.2 BeV = 10.2 × 109 eV Energy of each y-ray photon is E = 5.1 × 109 eV = 5.1 x 109 x 1.6 x 10-19 J = 5.1 × 1.6 x 10-10 J But E = hv = \cfrac { hc }{ \lambda }  Hence, wavelength associated with y-ray is
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 41
Question 25.
Estimating the following two numbers should be interesting. The first number will tell you why radio engineers do not need to worry much about ‘photons’. The second number tells you why our eye can never’eount photons’ even barely detectable light.
(a) The number of photons emitted per , second by a MW transmitter of 10 kW power emitting radio waves of length 500 m.
(b) The number of photons entering the pupil of our eye per second corresponding to the minimum intensity of white light that we humans can perceive (~ 10-10 W m-2). Take the area of the pupil ‘to be about 0.4 cm2 and the average frequency of white light to be about 6 × 1014 Hz.
Solution:
(a) Here, power of tansmitter,
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 42
exceedingly small and the number of photons emitted per second in a radio beam is enormously large. Therefore, negligible error involved in ignoring the existence of a minimum quantum of energy (photon) and treating the total energy of a radio wave as continuous.
(b) Here, area of the pupil, A = 0.4 cm2 = 0.4 × 10-4 m2, v = 6 × 1014 Hz Intensity = 10-10 W m-2 Energy of a photon is given by, E = hv = 6.63 × 10-34 × 6 × 1014 J = 4 × 10-19 J.
If n = number of photons falling per sec per unit area, the energy per unit area per sec due to these photons = total energy of n photons = n × 4 × 10-19 J nr2 Since, intensity = energy per unit area per second
10^{ -10 }=n\times 4\times { 10 }^{ -19 }
n=\frac { 10^{ -10 } }{ 4\times 10^{ -19 } } =2.5\times 10^{ 8 }m^{ -2 }s^{ -2 }
∴ Number of photons entering the pupil per second = n x area of the pupil = 2.5 × 108 × 0.4 × 10-4 s-1 = 104 s-1.
Though this number is not large as in part (a) above, it is large enough for us to ‘sense’ or ‘count’ the individual photons by our eye.

Question 26.
Ultraviolet light of wavelength 2271 A from a 100 W mercury source irradiates a photo-cell made of molybdenum metal. If the stopping potential is -1.3 V, estimate the work function of the metal. How would the photo-cell respond to a high intensity (~ 105 W m2) red light of wavelength 6328 A produced by a He-Ne laser?
Solution:
Let us find energy of each photon of given ultraviolet light
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 43
Maximum kinetic energy of emitted electron can be judged by stopping potential of 1.3 volt.
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 44
Thus energy of red light photons is less than work function 4.17 eV, hence irrespective of any intensity, no emission will take place.

Question 27.
Monochromatic radiation of wavelength 640.2 nm (1 nm = 10-9 m) from a neon lamp irradiates photosensitive material made of caesium on tungsten. The stopping voltage is measured to be 0.54 V.The source is replaced by an iron source and its 427.2 nm line irradiates the same photo-cell. Predict the new stopping voltage.
Solution:
From the first data, work function of given photosensitive material can be calculated.
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 45
Now the source is replaced by iron source which produce 427.2 nm wavelength.
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 46

Question 28.
A mercury lamp is a convenient source for studying frequency dependence of photoelectric emission, since it gives a number of spectral lines ranging from the UV to the red end of the visible spectrum. In our experiment with rubidium photo-cell, the following lines from a mercury source were used :
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 47
The stopping voltages, respectively, were measured to be:
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 48
Determine the value of Planck’s constant h, the threshold frequency and work function for the material.
Solution:
In order to calculate Planck’s constant ‘ll’ we need slope of the graph between cut off voltage and frequency. So, let us first calculate the frequency (u = c/λ) in each case and the table shows corresponding stopping potential.
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 49
V0 versus n plot shows that the first four points lie nearly on a straight line which intercepts the x-axis at threshold frequency, u0 = 5.0 × 1014 Hz. The fifth point u (= 4.3 × 1014 Hz) corresponds to u < u0, so there is no photoelectric emission and no stopping voltage is required to stop the current.
Slope of, V0 versus u graph is
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 50
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 51
(b) threshold frequency, v0 = 5.0 × 1014 J
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 52
Question 29.
The work function for the following metals is given:
Na: 2.75 eV; K: 2.30 eV; Mo: 4.17 eV; Ni: 5.15 eV. Which of these metals will notgive photoelectric emission for a radiation of wavelength 3300 A from a He-Cd laser placed 1 m away from the photocell? What happens if the laser is brought nearer and placed 50 cm away?
Solution:
The distance between laser source and receiver does not affect the energy of each photon incident, hence does not affect the energy of emitted photo electrons. But the reduction in distance will increase the intensity of incident light and hence number of photons. This will increase the photoelectric current. where, wavelength of incident radiation is
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 53
Now, work function of Mo: 4.17 eV, Ni: 5.15 eV is more than energy of incident photon, hence these two metals will not give photoelectric emission.

Question 30.
Light of intensity 10-5 W m-2 falls on a sodium photo-cell of surface area 2 cm2. Assuming that the top 5 layers of sodium absorb the incident energy, estimate time required for photoelectric emission in the wave-picture of radiation. The work function for the metal is given to be about 2 eV. What is the implication of your answer?
Solution:
Wave picture of radiation state that incident energy is uniformly distributed among all the electrons continuously. Let us first calculate the total number of recipient electrons in-5 layers of sodium. Consider each sodium atom has one electron free as conduction electron. Effective atomic area = 10-20 m2 Number of conduction electrons in 5 layers
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 54
Where experimental observation shows that emission of photo electrons is instantaneous = 10-9 sec Thus wave picture fails to explain photoelectric effect.

Question 31.
Crystal diffraction experiments can be perfor- med using X-rays, or electrons accelerated through appropriate voltage. Which probe has greater energy? An X-ray photon or the electron? (For quantitative comparison, take the wavelength of the probe equal to 1 A, which is of the order of inter-atomic spacing in the lattice) (me = 9.11 × 10-31 kg).
Solution:
Order of interatomic spacing is 1 A in the crystal lattice. So, for diffraction to take place the wavelength should be of the same . order. For X-ray photon (energy for wavelength of 1 A)
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 55
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 56
Thus in order to produce same wavelength X-ray photon should have higher energy than electron.

Question 32.
(a) Obtain the de Broglie wavelength of a neutron of kinetic energy 150 eV. An electron beam of this energy is suitable for crystal diffraction experiments. Would a neutron beam of the same energy be equally suitable? Explain. (mn = 1.675 × 10-27 kg)
(b) Obtain the de Broglie wavelength associated with thermal neutrons at room temperature (27°C). Hence explain why a fast neutron beam needs to be thermalised with the environment before it can be used for neutron diffraction experiments.
Solution:
(a) Let us first calculate the wavelength of matter wave associated with neutron of kinetic energy 150 eV.
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 57
As the inter atomic spacing (1 A= 10-10 m) is about hundred times greater than this wavelength, so a neutron beam of 150 eV energy is not suitable for diffraction experiments.

(b) Average kinetic energy of a neutron at absolute temperature T is
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 58
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 59
As this wavelength is comparable to inter atomic spacing (= 1 A) in a crystal, so thermal neutrons can be used for diffraction experiments. So high energy neutron beam should be first thermalised before using it for diffraction.

Question 33.
An electron microscope uses electrons accelerated by a voltage of 50 kV. Determine the de-Broglie wavelength associated with the electrons. If other factors (such as numerical aperture etc.) are taken to be roughly the same, how does the resolving power of an electron microscope compare with that of an optical microscope which uses yellow light?
Solution:
K.E. of an electron, accelerated by voltage of 50 kV.
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 60
Thus, the resolving power of an electron microscope is about 103 times greater than that of an optical microscope.

Question 34.
The wavelength of a probe is roughly a measure of the size of a structure that it can probe in some detail. The quark structure of protons and neutrons appears at the minute length scale of 10-15 m or less. This structure was first probed in early 1970’s using high energy electron beam produced by a linear accelerator at Stand ford, USA. Guess what might have been the order of energy of these electron beams. (Rest mass energy of electron = 0.511 M eV).
Solution:
Momentum of electron associated with given wavelength
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 61
Second term showing rest mass energy is negligible. Energy, E = 1.989 × 10-10 J = 1.24 BeV Thus, energies acquired by electron from the given accelerator must have been of the order of a few BeV.

Question 35.
Find the typical de-Broglie wavelength associated with a He atom in helium gas at room temperature (27°C) and 1 atm pressure; and compare it with the mean separation between two atoms under these conditions.
Solution:
Let us first find mass ‘in’ of each helium atom.
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 62
Wavelength of the wave associated with He atom at room.temperature
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 63
Now let us find mean separation between He atoms. mean separation,
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 64
Comparing the wavelength ‘X’ with mean separation V, it can be observed that separa¬tion is larger than

Question 36.
Compute the typical de Broglie wavelength of an electron in a metal at 27° C and compare it with the mean separation between two electrons in a metal which is given to be about 2 × 10-10 m.
Solution:
Considering free electrons as gas. Kinetic energy at temperature T
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 65
Given that mean separation between two electrons is about 2 × 10-10 m.
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 66
So, de-Broglie wavelength is much greater than the electron separation.

Question 37.
Answer the following questions:
(a) Quarks inside protons and neutrons are thought to carry fractional charges [(+ 2/3)e ; {—1/3)e]. Why do they not show up in Millikan’s oil-drop experiment?
(b) What is so special about the combination e/m? Why do we not simply talk of e and m separately?
(c) Why should gases be insulators at ordinary pressures and start conducting at very low pressure?
(d) Every metal has a definite work function. Why do all photo electrons not come out with the same energy if incident radiation is monochromatic? Why is there an energy distribution of photo electrons?
(e) The energy and momentum of an electron are related to the frequency and wavelength of the associated matter wave by the relations: E = hv, p = h/λ
But while the value of X is physically significant, the value of u (and therefore, the value of phase speed uλ) has no physical significance. Why?
Solution:
(a) The quarks having fractional charges are thought to be confined within a proton and a neutron. These quarks are bound by forces. These forces become stronger when the quarks are tried to be pulled apart. That is why, the quarks always remain together. It is due to this reason that though fractional charges do exist in nature but the observable charges are always integral multiple of charge of electron.

(b)
 The motion of electron in the electric and magnetic field is related with the basic equations
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 67
All these equations involve e and m together, i.e., there is no equation in which e or m occurring alone. As a result of it, we study e/m of electron and do not talk of e and m separately for an electron.

(c)
 At ordinary pressures a few positive ions and electrons produced by the ionisation of the gas molecules by energetic rays (like X-rays, y-rays, cosmic rays etc. coming from outer space and entering the earth’s atmosphere) are not able to reach their respective electrodes, even at high voltages, due to their frequent collisions with gas molecules and recombinations. That is why the gases at ordinary pressures are insulators.
At low pressures, the density of the gas decreases, the mean free path of the gas molecules become large. Now under the effect of external high voltage, the ions acquire sufficient energy before they collide with molecules causing further ionisation. Due to it, the number of ions in the gas increases and it becomes a conductor.

(d)
 By work function of a metal, we mean the minimum energy required for the electron
in the highest level of conduction band to get out of the metal. Since all the electrons in the metal do not belong to that level but they occupy a continuous band of levels, therefore, for the given incident radiation, electrons knocked off from different levels come out with different energies.

(e)
 de broglie wavelength associated with the moving particle is
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 68
Energy of the wave is E= hv = \cfrac { hc }{ \lambda } Energy of moving particle
NCERT Solutions for Class 12 Physics Chapter 11 Dual Nature of Radiation and Matter 69

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Class 12th Chapter -10 Wave Optics |NCERT Physics Solutions | Edugrown

NCERT Solutions for Class 12 Physics Chapter – 10 Wave Optics includes all the important topics with detailed explanation that aims to help students to understand the concepts better. Students who are preparing for their Class 12 exams must go through NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics. Going through the solutions provided on this page will help you to know how to approach and solve the problems.

Students can also find NCERT intext, exercises and back of chapter questions. Also working on Class 12 Physics Chapter 10 NCERT Solutions will be most helpful to the students to solve their Home works and Assignments on time.

NCERT Solutions for Class 12 Physics Chapter : 10 Wave Optics

NCERT Exercises

Question 1.
Monochromatic light of wavelength 589 nm is incident from air on a water surface. What are the wavelength, frequency and speed of
(a) reflected, and
(b) refracted light? Refractive index of water is 1.33.
Solution:
(a) In the process of reflection wavelength, frequency and speed of incident light remain unchanged. So, speed of reflected light = speed of incident light
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 1
(b) In the process of refraction wavelength and speed changes but the frequency remain the same. Speed of light in water
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 2

Question 2.
What is the shape of the wave front in each of the following cases:
(a) Light diverging from a point source.
(b) Light emerging out of a convex lens when a point source is placed at its focus.
(c) The portion of the wave front of light from a distant star intercepted by the Earth.
Solution:
(a) Spherical wave front : All particles vibrating in same phase will lie on a sphere.
(b) Plane wave front: Light will be a parallel beam after passing through the convex lens.
(c) Plane wave front : Light rays from a distant star are nearly parallel as a small portion of a huge spherical wave front is nearly plane.

Question 3.
(a) The refractive index of glass is 1.5. What is the speed of light in glass? (Speed of light in vacuum is 3.0 × 108 m s-1)
(b) Is the speed of light in glass independent of the colour of light? If not, which of the two colours, red and violet, travels slower in a glass prism?
Solution:
(a) Speed of light in glass,
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 3
(b) Yes, speed of light in glass depends upon the colour of light (i.e., λ). Thus, speed of light is different for red and violet colours. As µv > µR so, λv < λR hence, υv < υR Speed of red colour is more than violet colour light in glass.

Question 4.
In a Young’s double-slit experiment, the slits are separated by 0.28 mm and the screen is placed 1.4 m away. The distance between the central bright fringe and the fourth bright fringe is measured to be 1.2 cm. Determine the wavelength of light used in the experiment.
Solution:
Here d = 0.28 mm, D = 1.4 m Distance of fourth bright fringe from center
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 4
Question 5.
In Young’s double-slit experiment using monochromatic light of wavelength X, the intensity of light at a point on the screen where path difference is X, is K units. What is the intensity of light at a point where path difference is λ/3?
Solution:
In Young’s double-slit experiment net intensity of light at a point on screen is
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 5
Question 6.
A beam of light consisting of two wavelengths, 650 nm and 520 nm is used to obtain interference fringes in a Young’s double-slit experiment.
(a) Find the distance of the third bright fringe on the screen from the central maximum for wavelength 650 nm.
(b) What is the least distance from the central maximum where the bright fringes due to both the wavelengths coincide?
Solution:
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 6
(a) Distance of third bright fringe from the central maximum for the wavelength 650 nm.
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 7
(b) Let at linear distance ‘y’ from center of screen the bright fringes due to both wavelength coincides. Let n1 number of bright fringe with wavelength λ1 coincides with n2 number of bright fringe with wavelength λ2. We can write
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 8
Also at first position of coincide, the nth bright fringe of one will coincide with (n + l) th bright fringe of other.
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 9
So, the fourth bright fringe of wavelength 520 nm coincides with 5th bright fringe of wavelength 650 nm.

Question 7.
In a double-slit experiment the angular width of a fringe is found to be 0.2° on a screen placed 1 m away. The wavelength of light used is 600 nm. What will be the angular width of the fringe if the entire experimental apparatus is immersed in water? Take refractive index of water to be 4/3.
Solution:
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 10
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 11
Question 8.
What is the Brewster angle for air to glass transition? (p for glass is 1.5)
Solution:
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 12
Question 9.
Light of wavelength 5000 A falls on a plane reflecting surface. What are the wavelength and frequency of the reflected light? For what angle of incidence is the reflected ray normal to the incident ray?
Solution:
In the reflected light the wavelength and frequency remain the same as that of incident light. Wavelength of reflected light = 5000 A, frequency of reflected light
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 13
For an angle of incidence 45° the reflected ray is normal to incident ray.

Question 10.
Estimate the distance for which ray optics is good approximation for an aperture of 4 mm and wavelength 400 nm.
Solution:
Fresnel distance required for a sufficient spreading of central bright fringe, so that diffraction is appreciable
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 14
So, for distance less than 40 m between slit and screen, ray optics is a good approximation as within this distance, the spreading is negligible.

Question 11.
The 6563 A Ha line emitted by hydrogen in a star is found to be red shifted by 15 A. Estimate the speed with which the star is receding from the earth.
Solution:
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 15
Since the star is receding away, hence its velocity v is negative (i.e. if AA is positive, v is negative)
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 16
Here, negative sign shows recession of star.

Question 12.
Explain how corpuscular theory predicts that the speed of light in a medium, say, water, is greater than the speed of light in vacuum. Is the prediction confirmed by experimental determination of the speed of light in water? If not, which alternative picture of light is consistent with experiment?
Solution:
In Newton’s corpuscular (particle) picture of refraction, particles of light incident from a rarer to a denser medium experience a force of attraction normal to the surface. This results in an increase in the normal component of velocity but the component along the surface remains unchanged.
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 17
Considering a ray of light going from a rarer medium (air) to a denser medium (water). Let c = speed of light in vacuum (or air), v = speed of light in water, i = angle of incidence, and r = angle of refraction Then according to Newton’s corpuscular theory,

Component of velocity c along surface of separation = Component of velocity v along the surface of separation
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 18

So, according to Newton’s corpuscular theory the speed of light in medium is larger than speed of light in air. υ > c but in fact the experimental observation shows that speed of light is smaller in denser medium as compared to rare medium υ < c.

Question 13.
You have learnt in the text how Huygens principle leads to the laws of reflection and refraction. Use the same principle to deduce directly that a point object placed in front of a plane mirror produces a virtual image whose distance from the mirror is equal to the distance of the object from the mirror.
Solution:
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 19
In figure, P is a point object placed at a distance . r from a plane mirror M1M2. With P as centre and PO = r as radius, draw a spherical arc; AB. This is the spherical wave front from the object, incident on M1M2 If mirrors were not present, the position of wave front AB would be A’B’ where PP’ = 2r. In the presence of the mirror, wave front A B would appear as A”PB”, according to Huygen’s construction. As it is clear from the figure A’B’ and A”B” are two spherical arcs located symmetrically on either side of M1M2. , Therefore, A’P’B’ can be treated as reflected image of A”PB”. From simple geometry, we find OP = OP’, which was to be proved.

Question 14.
Let us list some of the factors, which could possibly influence the speed of wave propagation:
(i) nature of the source.
(ii) direction of propagation.
(iii) motion of the sources and/or observer.
(iv) wavelength.
(v) intensity of the wave. On which of these factors, if any, does
(a) the speed of light in vacuum,
(b) the speed of light in a medium (say glass or water) depend?
Solution:
(a) Speed of light in vacuum is independent of all the factors listed above. It is also independent of relative motion between source and observer.
(b) Dependence of speed of light in a medium.
(i) The speed of light in a medium does not depend on the nature of the source. Although speed is determined by the properties of the medium of propagation.
(ii) The speed of light in a medium is independent of the direction of propagation for an isotropic media.
(iii) The speed of light is independent of the motion of the source relative to the medium but it depends upon the motion of the observer relative to the medium.
(iv) The speed of light in a medium depends on wavelength of light i.e., v ∝ λ..
(v) The speed of light in a medium is independent of intensity.

Question 15.
For sound waves, the Doppler formula for frequency shift differs slightly between the two situations :
(i) source at rest; observer moving, and
(ii) source moving; observer at rest.
The exact Doppler formulas for the case of light waves in vacuum are, however, strictly identical for these situations. Explain why this should be so. Would you expect the formulas to be strictly identical for the two situations in case of light travelling in a medium?
Solution:
Sound waves require a medium for propagation. The Doppler formula for frequency shift differs slightly in two situations
(i) Source at rest, observer moving
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 20
(ii) Observer at rest, source moving
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 21
The two formulas are different because motion of the observer relative to the medium is different in the two situations for light waves in vacuum. No such relative relation of observer and medium exist. Hence only the relative motion between the source and the observer counts and the
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 22
Question 16.
In double-slit experiment using light of wavelength 600 nm, the angular width of a fringe formed on a distant screen is 0.1°. What is the spacing between the two slits?
Solution:
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 23
Question 17.
Answer the following questions:
(a) In a single slit diffraction experiment, the width of the slit is made double the original width. How does this affect the size and intensity of the central diffraction band?
(b) In what way is diffraction from each slit related to the interference pattern in a double-slit experiment?
(c) When a tiny circular obstacle is placed in the path of light from a distant source, a bright spot is seen at the centre of the shadow of the obstacle. Explain why?
(d) Two students are separated by a 7 m partition wall in a room 10 m high. If both light and sound waves can bend around obstacles, how is it that the students are unable to see each other even though they can converse easily.
(e) Ray optics is based on the assumption that light travels in a straight line. Diffraction effects (observed when light propagates through small apertures/slits or around small obstacles) disprove this assumption. Yet the ray optics assumption is so commonly used in understanding location and several other properties of images in optical instruments. What is the justification?
Solution:
(a) Linear width of central maximum
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 24
On doubling the slit width ‘d’, the size of central diffraction band is halved.
Because the width of central maximum is halved. Its area become 1/4 times and hence the intensity become 4 times the initial intensity.
(b) In double slit experiment, an interference pattern is observed by waves from two slits but as each slit provide a diffraction pattern of its own, thus the intensity of interference pattern in Young’s double slit experiment is modified by diffraction pattern of each slit.
(c) Waves from the distant source are diffracted by the edge of the circular obstacle and these waves superimpose constructively at the centre of obstacle’s shadow producing a bright spot.
(d) We know for diffraction to take place, size of the obstacle/aperture should be of the order of wavelength. Wavelength of sound waves is of the order of few meters that is why sound waves can bend through the aperture in partition wall but wavelength of light waves is of the order of micrometer, hence light waves can not bend through same big aperture. That is why the two students can hear each other but cannot see each other.
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 25
(e) In optical instruments, the sizes of apertures are much larger as compared to wavelength of light. So the diffraction effects are negligibly small. Hence, the assumption that light travels in straight lines is used in the optical instruments.

Question 18.
Two towers on top of two hills are 40 km apart. The line joining them passes 50 m above a hill halfway between the towers. What is the longest wavelength of radio waves, which can be sent between the towers without appreciable diffraction effects?
Solution:
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 26
For diffraction of radio waves not to occur the distance of middle hill should be less than fresnel distance for a slit width ‘a’ of 50 m.
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 27
Distance between one of the towers and the hill halfway in between
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 28
Longest wavelength of radio wave which can be sent without appreciable diffraction effect
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 29
Thus wavelength of radio waves longer than 12.5 cm will bend due to the hill in the middle of towers.

Question 19.
A parallel beam of light of wavelength 500 nm falls on a narrow slit and the resulting diffraction pattern is observed on a screen 1 m away. It is observed that the first minimum is at a distance of 2.5 mm from the centre of the screen. Find the width of the slit.
Solution:
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 30
First minimum is observed at a distance 2.5 mm from centre of the screen.
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 31
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 32
Question 20.
Answer the following questions:
(a) When a low-flying aircraft passes overhead, we sometimes notice a slight shaking of the picture on our TV screen. Suggest a possible explanation.
(b) As you have learnt in the text, the principle of linear superposition of wave displacements is basic to understanding intensity distributions in diffraction and interference patterns. What is the justification of this principle?
Solution:
(a) The low flying aircraft reflects the TV signals. Due to superposition between the direct signal received by the antenna and the reflected signals from aircraft. We sometimes notice slight shaking of the picture on the TV screen.
(b) Superposition principle states how to explain the formation of resultant wave by combination of two or more waves. Let and y2 represent instantaneous displacement of two superimposing waves, then resultant waves instantaneous displacement is given by
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 33
Question 21.
In deriving the single slit diffraction pattern, it was stated that the intensity is zero at angles of nλ/a. Justify this by suitably dividing the slit to bring out the cancellation.
Solution:
Let the single-slit of width a be divided into n smaller slits. If a’ is the width of each one of the smaller slits, a’ = a/n. For the single¬slit to produce zero intensity, each one of the smaller slits should also produce zero intensity? This is possible if
NCERT Solutions for Class 12 Physics Chapter 10 Wave Optics 34

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